SDS

SECTION
SECTION
SECTION
SECTION 4
4
4
4 --
--
--
-- FIRST
FIRST
FIRST
FIRST AI
AI
AI
AID
D
D
D MEASURES
MEASURES
MEASURES
MEASURES
Emergency and First Aid
Procedures
Contact with internal components if battery is opened, broken or spilled.
1. Inhalation Remove to fresh air and provide medical oxygen/CPR if needed. Obtain medical attention.
2. Eyes Immediately flush with water for at least 15 minutes, hold eyelids open. Obtain medical attention.
3. Skin Flush contacted area with large amounts of water for at least 15 minutes. Remove contaminated clothing and
obtain medical attention if
necessary.
4. Ingestion Do not induce vomiting. If conscious drink large amounts of water/milk. Obtain medical attention. Never give anything by mouth to
an unconscious person.
SECTION
SECTION
SECTION
SECTION 5
5
5
5 --
--
--
-- FIREFIGHTING
FIREFIGHTING
FIREFIGHTING
FIREFIGHTING ME
ME
ME
MEASURES
ASURES
ASURES
ASURES
Flash Point – Not
Applicable
Flammable Limits in Air Hydrogen Lower Upper
% by Volume: (H
2
) 4.1% 74.2%
( when charging)
Extinguishing Media Class ABC,
CO
2
, HALON.
Auto-Ignition 675
°
F
(polypropylene) Temperature
Special Fire Fighting
Procedures
Lead/acid batteries do not burn, or burn with difficulty. Do not use water on fires where molten metal is present. Extinguish fire with agent
suitable
for surrounding combustible materials. Cool exterior of battery if exposed to fire to prevent rupture. The acid mist and vapors generated by heat
or fire are corrosive. Use NIOSH approved self-contained breathing apparatus (SCBA) and full protective equipment operated in positive-pressure
Unusual Fire and
Explosion Hazards
Hydrogen gas and sulfuric acid vapors are generated upon overcharge (when filled with electrolyte) and polypropylene case failure. Ventilate
charging areas as per ACGIH Industrial Ventilati
on A Manual of Recommended Practice and National Fire Code, 1980 Vol. 1, P. 12, B-9, 10.
Hydrogen gas may be flammable or explosive when mixed with air, oxygen, chlorine. To avoid risk of fire or explosion, keep sparks or other
sources of ignition away from batteries and do not allow metallic materials to simultaneously contact negative and positive terminals of cells and
batteries. SULFURIC ACID REACTS VIOLENTLY WITH WATER/ORGANICS.
SECTION
SECTION
SECTION
SECTION 6
6
6
6 --
--
--
-- ACCIDENTA
ACCIDENTA
ACCIDENTA
ACCIDENTAL
L
L
L RELEAS
RELEAS
RELEAS
RELEASE
E
E
E MEASURES
MEASURES
MEASURES
MEASURES
Procedures
Procedures
Procedures
Procedures for
for
for
for Cleanup
Cleanup
Cleanup
Cleanup: Stop release, if possible. Avoid contact with any spilled material. Contain spill, isolate hazard area, and deny entry. Limit site access
to emergency responders. Neutralize with sodium bicarbonate, soda ash, lime or other neutralizing agent. Place battery in suitable container for disposal. Dispo
se
of
contaminated material in accordance with applicable local, state and federal regulations. Sodium bicarbonate, soda ash, sand, lime or other neutralizing agent should be kept
on-site for spill remediation.
Personal
Personal
Personal
Personal Precautions
Precautions
Precautions
Precautions: Acid resistant aprons, boots and protective clothing. ANSI approved safety glasses with side shields/face shield recommended. Ventilate enclosed
areas.
Environmental
Environmental
Environmental
Environmental Precautions
Precautions
Precautions
Precautions
: Lead and its compounds and sulfuric acid are a severe threat to the environment. Contamination of water, soil and air should be prevented.
SECTION
SECTION
SECTION
SECTION 7
7
7
7 --
--
--
-- HANDLIN
HANDLIN
HANDLIN
HANDLING
G
G
G AN
AN
AN
AND
D
D
D STORAGE
STORAGE
STORAGE
STORAGE
Precautions to be Taken
in Handling and
Storage
Keep away from flames during and immediately after charging. Combustion or overcharging may create or liberate toxic and hazardous gases
and liquids including hydrogen, sulfuric acid mist, sulfur dioxide, sulfur t
rioxide, stibine, arsine and sulfuric acid. Store batteries in cool, dry, well-
ventilated areas. Do not short circuit battery terminals, or remove vent caps during storage or recharging. Protect battery from physical
damage.
Other Precautions GOOD PERSONAL HYGIENE AND WORK PRACTICES ARE MANDATORY. Refrain from eating, drinking or smoking in work areas.
Thoroughly wash hands, face, neck, and arms before eating, drinking or smoking. Work clothes and equipment should remain in designated
lead contaminated areas, and never taken home
or laundered with personal clothing. Wash soiled clothing, work clothes and equipment before
reuse. Emptied batteries contain hazardous sulfuric acid residue.
SECTION
SECTION
SECTION
SECTION 8
8
8
8 --
--
--
-- EXPOSURE
EXPOSURE
EXPOSURE
EXPOSURE CONTROLS
CONTROLS
CONTROLS
CONTROLS AN
AN
AN
AND
D
D
D P ERSONA
PERSONA
PERSONA
PERSONAL
L
L
L PROTECTION
PROTECTION
PROTECTION
PROTECTION
Respiratory
Protection
(Specify Type)
Acid/gas NIOSH approved respirator is required when the PEL is exceeded or employee experiences respiratory irritation. When exposure levels are
unknown or when firefighting, wear a self-contained breathing apparatus with a full facepiece operated in a positive pressure mode.
Vent
ilation Must be provided when charging in an enclosed
area.
Change air every 15 minutes.
Local Exhaust When PEL is exceeded. Mechanical
(General)
Normal mechanical ventilation
recommended for stationary
applications.
Protective
Gloves
Wear rubber or plastic acid resistant gloves with
elbow length gauntlet when filling batteries.
Eye Protection ANSI approved safety glasses with side shields/face shield recommended.
Other
Protective
Clothing or
Equipment
Ventilation, as described in the Industrial Ventilation Manua
l produced by the American Conference of Governmental Industrial Hygienists, shall be
provided in areas where exposures are above the PEL or TLV specified by OSHA or other local, state and federal regulations. Acid-resistant rubber or
plastic apron, boots and protective clothing. Safety shower and eyewash.
SECTION
SECTION
SECTION
SECTION 9
9
9
9 --
--
--
-- PHYSIC
PHYSIC
PHYSIC
PHYSICA
A
A
AL
L
L
L AN
AN
AN
AND
D
D
D CHEMICA
CHEMICA
CHEMICA
CHEMICAL
L
L
L PROPERTIES
PROPERTIES
PROPERTIES
PROPERTIES
Boiling Point: Electrolyte
Approx: 235
°
F
Vapor Electrolyte 1 mm HG @ 145.8
°
F
Pressure
Specific Electrolyte (H
2
O =
1)
Gravity 1.250-1.320 pH < 2
Melting Point: <320
°
F (polypropylene)
Percent Volatile Not Applicable
By Volume
Vapor Hydrogen (Air = 1) : 0.069
Density Electrolyte (Air =1) : 3.4 @ STP
Evaporation Not applicable
Rate
Solubility Elect
rolyte: 100% soluble
In water
Reactivity in Water Electrolyte – water reactive (1)
Appearance and Odor: Battery: Polypropylene or hard rubber case, solid.
Lead:
Electrolyte: Liquid, colorless, oily fluid; nuisance odor when hot or charging battery.
Gray, metallic, solid.