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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

Natriumper sulfat

Version 3.1 Print Date 16.10.2011

Revision Date 07.04.2011

R5566 1/17 EN

1. Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Trade name

Natriumpersulfat

Substance name

Disodium peroxodisulphate

CAS

No.

7775

No.

231

892

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the

Substance/Mixture

At this time we do not yet have information on identified uses.

They will be included in this safety data sheet when available.

Recommended

restrictions on use

At that time we do not yet have information on use restrictions.

They will be included in this safety data sheet when available.

1.3. Details of the supplier of the safety data sheet

Company

Brenntag GmbH

Stinnes-Platz 1

DE 45472 Muelheim an der Ruhr

Telephone

+49 (0)208

7828

Telefax

+49 (0)208

7828

7299

mail address

InfoSDB@brenntag.de

Responsible/issuing

person

Umwelt / Sicherheit

1.4. Emergency telephone number

Emergency telephone

number

+49 (0)208

7828

0 Available 24h/7d

2. Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

REGULATION (EC) No 1272/2008

Hazard class Hazard category Target Organs

Hazard

statements

Summary of content (17 pages)

PAGE 1
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.2011 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name Substance name CAS-No. EC-No. 1.2. 1.3. 1.4.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.2011 Hazard statements : H272 H302 H315 H317 H319 H334 May intensify fire; oxidiser. Harmful if swallowed. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.2011 Classification (REGULATION (EC) No 1272/2008) Hazardous components Amount [%] Hazard class / Hazard category Hazard statements Classification (67/548/EEC) Disodium peroxodisulphate CAS-No. EC-No. C&L-No. : 7775-27-1 : 231-892-1 : 02-2119752894-25-0000 Ox. Sol.3 Acute Tox.4 Eye Irrit.2 STOT SE3 Skin Irrit.2 Resp. Sens.1 Skin Sens.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.2011 4.3. Symptoms : Skin irritation, Severe eye irritation, Allergic reactions, Respiratory irritation, Asthmatic appearance Effects : Harmful if swallowed. Indication of any immediate medical attention and special treatment needed Treatment 5. Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.2011 Avoid dust formation. 6.2. Environmental precautions Environmental precautions 6.3. : Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. If the product contaminates rivers and lakes or drains inform respective authorities. If material reaches soil inform authorities responsible for such cases.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.2011 7.3. Advice on protection against fire and explosion : Oxidising. Keep away from combustible material. Further information on storage conditions : Keep away from heat. Keep away from direct sunlight. Avoid moisture. Protect from contamination. Product is hygroscopic. German storage class : 5.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.2011 The following information applies to aqueous, saturated solutions. The glove material has to be impermeable and resistant to the product / the substance / the preparation.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.2011 General advice : Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. If the product contaminates rivers and lakes or drains inform respective authorities. If material reaches soil inform authorities responsible for such cases. 9. Physical and chemical properties 9.1.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.2011 Water solubility 9.2. : 556 g/l (20 °C soluble Partition coefficient: n-octanol/water : not applicable Ignition temperature : no data available Thermal decomposition : > 180 °C Viscosity, kinematic : not applicable Explosive properties : EU legislation: Not explosive Oxidizing properties : May intensify fire; oxidiser.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.2011 Materials to avoid : Impurities Heavy metal salts Acids alkalis Reducing agents Organic materials flammable substances 10.6. Hazardous decomposition products Hazardous decomposition : Fire may cause evolution of: products Sulphur oxides 11. Toxicological information 11.1. Information on toxicological effects Acute toxicity Oral : : Harmful if swallowed.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.2011 Eyes Result : Causes serious eye irritation. Sensitisation Result : May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Component: Disodium peroxodisulphate CAS-No. 7775-27-1 Acute toxicity Oral LD50 : 920 mg/kg (rat) Inhalation LC50 : > 5,1 mg/l (rat; 4 h) Dermal LC50 12.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.2011 LC50 : 163 mg/l (96 h) Toxicity to daphnia and other aquatic invertebrates. EC50 : 133 mg/l (Daphnia; 48 h) algae IC10 : 33 mg/l (scenedesmus quadricauda; 96 h) Bacteria EC10 : 36 mg/l (Pseudomonas putida) (Toxicity to bacteria) EC10 : 1000 mg/l (Bacteria) (Toxicity to bacteria) 12.2.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.2011 12.5. Results of PBT and vPvB assessment Results of PBT and vPvB assessment Result : no data available 12.6. Other adverse effects Additional ecological information Result : slightly water endangering Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. Component: Disodium peroxodisulphate CAS-No.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.2011 14.1. UN number 1505 14.2. UN proper shipping name ADR RID IMDG : SODIUM PERSULPHATE : SODIUM PERSULPHATE : SODIUM PERSULPHATE 14.3. Transport hazard class(es) ADR-Class (Labels; Classification Code; Hazard identification No; Tunnel restriction code) RID-Class (Labels; Classification Code; Hazard identification No) IMDG-Class (Labels; EmS) : 5.1 5.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.2011 15. Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture WGK (DE) : WGK Identification Number: 1,352; WGK:1; slightly water endangering; WGK (DE); Classification according VwVwS of 17 May 1999, Annex 2 Major Accident Hazard Legislation : 3 Falls under the German StörfallV.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Natriumpersulfat Version 3.1 Print Date 16.10.2011 Revision Date 07.04.2011 Further information Other information : The information provided in this Safety Data Sheet is correct to our knowledge at the date of its revision. The information given only describes the products with regard to safety arrangements and is not to be considered as a warranty or quality specification and does not constitute a legal relationship.