SDS

ManualsBrandsQFX ManualsElectricalRetro Ford Truck Portable Bluetooth Speaker (Black)

SAMSUNG SDI Co., Ltd.

Date: Jan 7

2020 Revision no.: 01

ELG(P11P35-11-N01,3.7L1200SPA)

Page 1 of 22

Safety Data Sheet

Regulation : In accordance with Regulation (EU) 2015/830 (REACH), Annex II, and OSHA 29 CFR

1910.1200

Section I – IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF

THE COMPANY/UNDERTAKING

Important Note: As a solid, manufactured article, exposure to hazardous ingredients is not expected with

normal use. This battery is an article pursuant to 29 CFR 1910.1200 and, as such, is not subject to the

OSHA Hazard Communication Standard requirement. The information contained in this Safety Data Sheet

contains valuable information critical to the safe handling and proper use of the product. This SDS should be

retained and available for employees and other users of this product.

1.1 Product identifier

Substance name : ELG(P11P35-11-N01,3.7L1200SPA)

Synonyms :

Lithium-ion Cell, Lithium-ion Battery, Li-Ion Cell, Li-Ion Battery

1.2 Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses : Lithium-ion batteries

Uses advised against : Use for recommended use only

Further Information : Not available

1.3 Details of the supplier of the safety data sheet

Supplier : SAMSUNG SDI Co., Ltd.

Street address/P.O. Box : 150-20, Gongse-ro, Giheung-gu, Yongin-si, Gyeonggi-do, Korea

Country ID/Postcode/Place :

Telephone number : 1-800-424-9300: US and Canada / 1-703-527-3887: International

Responsible Department: Quality team

e-mail address of competent person responsible for the SDS : Not available

National contact : 1-800-424-9300: US and Canada / 1-703-527-3887: International

1.4 Emergency Telephone

: 1-800-424-9300: US and Canada / 1-703-527-3887: International

Opening hours : Not available

Other comments : Not available

1.5 Further Information

Battery-System: Lithium-ion (Li-ion)

Nominal Voltage: 3.7 V

Rated Capacity: 1.200 Ah

Wh rating: 4.44 Wh

Anode (negative electrode): based on intercalation graphite

Cathode (positive electrode): based on lithiated metal oxide (Cobalt)

Remark:

Summary of content (22 pages)

PAGE 1
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) Safety Data Sheet Regulation : In accordance with Regulation (EU) 2015/830 1910.1200 (REACH), Annex II, and OSHA 29 CFR Section I – IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Important Note: As a solid, manufactured article, exposure to hazardous ingredients is not expected with normal use. This battery is an article pursuant to 29 CFR 1910.
PAGE 2
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation. SAMSUNG SDI Co., Ltd. makes no warranty, expressed or implied, with respect to this information and disclaims all liabilities from reliance on it.
PAGE 3
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) exposure occurs only if the cell or pack is mechanically, thermally, electrically or physically abused to the point of compromising the enclosure. If this occurs, exposure to the electrolyte solution contained within can occur by inhalation, ingestion, eye contact and skin contact. Potential Health Effect(s): Acute (short term): see Section 8 for exposure controls.
PAGE 4
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) 4.1 Description of first aid measures Following eye contact : - Rinse eyes with plenty of water for at least 15 minutes and seek medical attention. Following skin contact : - Remove contaminated clothing and wash before reuse. - Immediately rinse contact area with plenty of clean water. - Provide first aid to contacted area to prevent infection. - Get medical attention.
PAGE 5
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) - The ignited battery has a high temperature, so there is a risk of additional ignition even if the fire is extinguished at early stage. Sprinkle a large amount of water until the battery temperature drops to normal temperature.
PAGE 6
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) Section VII – HANDLING AND STORAGE 7.1 Precautions for safe handling - In case of cell damage, possible release of dangerous substances and a flammable gas mixture. - The battery stores electrical energy and is capable of rapid energy discharge. - Battery cell contents are under pressure. - Handle battery carefully to avoid puncturing case or electrically shorting terminals. 7.
PAGE 7
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) lithium carbonate Copper Ethyl methyl carbonate tricobalt tetraoxide Not applicable Not available Not applicable Not applicable Not applicable TWA = 0.2 mg/m³ Not available (fume) Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not available TWA = 0.2 mg/m³ (Cobalt and cobalt Not available compounds,CAS. no7440-48-4) TWA = 0.1 mg/m³ TWA = 0.
PAGE 8
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) (respirable particulate matter); TWA = 0.1 mg/m3 (inhalable particulate matter) (Manganese compounds (as Mn), Manganese fume (as Mn)) (inhalable fraction) 8.2 Exposure controls 8.2.1 Appropriate engineering controls : Substance/mixture related measures to prevent exposure during identified uses: - Avoid charging batteries in areas where hydrogen gas accumulate.
PAGE 9
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) - In lack of oxygen(< 19.5%), wear the supplied-air respirator or self-contained oxygen breathing apparatus. - In case exposed to particulate material, the respiratory protective equipments as follow are recommended; facepiece filtering respirator or air-purifying respirator, high-efficiency particulate air(HEPA) filter media or respirator equipped with powered fan, filter media of use (dust, mist, fume) 8.2.
PAGE 10
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) Section X – STABILITY AND REACTIVITY 10.1 Reactivity - Stable at ambient temperature. 10.2 Chemical stability - There is no hazard when the measures for handling and storage are followed. - Stable under normal temperatures and pressures. 10.3 Possibility of hazardous reactions - Will not occur under normal conditions. - In case of cell damage, possible release of dangerous substances and a flammable gas mixture.
PAGE 11
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) please note that these overall information is irrelevant to this product. 11.
PAGE 12
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) irritant.(OECD TG 404)(Read across; aluminium oxide) - Lithium carbonate;Lithane : In the skin irritation test using rabbits, the test material was not irritating. (OECD Guideline 404, GLP) - Copper : In test on skin irritation with rabbits, skin irritations were not observed. (OECD TG 404, GLP) - Ethyl methyl carbonate : In the skin irritation test using rabbits, the test material was not irritating.
PAGE 13
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) - Manganese : In test on eyes irritation with rabbits, eyes irritations were not observed.(OECD TG 405, GLP) Respiratory sensitization : - Aluminum : Al2O3 was the least inflammatory material tested and led to only weak effects on the mouse lung. (Read across; Aluminium oxide) - Carbon black : In respiratory sensitization test with mice(female), it did not induce respiratory sensitization.
PAGE 14
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) - Carbon black : Present - Nickel : Present ACGIH - Cobalt and cobalt compounds : A3 - Aluminum : A4 - Carbon black : A3 - Nickel : A5 - Manganese : A4 KOREA-ISHL - Cobalt and inorganic compounds : 2 - Carbon black : 2 - Nickel : 1A EU - Nickel : Carc. 2 Cobalt hydroxide oxide : Carcinogenicity studies using rats (male / female) revealed carcinogenic effects.
PAGE 15
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) Escherichia coli. - Carbonic acid diethyl ester : In vitro mammalian cell micronucleus test, positive reaction was observed.Diethyl carbonate showed clear evidence of genotoxic activity. (OECD TG 487, GLP) But, the substance is not classfied as mutagenicity because there are no datas in vivo genetic toxicity test.
PAGE 16
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) - Manganese : In the acute oral toxicity using rat, there were no effects on clinical signs, systemic toxicity.(OECD TG 420, GLP) Specific target organ toxicity (repeat exposure) : - Cobalt hydroxide oxide : Under the conditions of the 2-year inhalation study, there was some evidence of carcinogenic activity of cobalt sulfate heptahydrate in male F344/N rats.
PAGE 17
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) - Cobalt hydroxide oxide : 96hr-LC50 (Oncorhynchus mykiss) = 1.5 mg/L (ASTM guideline), NOEC=351.4µg/L - Graphite : 96hr-LC50 ＞ 100 mg/L - Aluminum : 96hr-LC50 ＞ 218.64 mg/L (GLP)(Read across; aluminium chloride hexahydrate), 28dNOEC (Pimephales promelas) = 4.7 mg/L (Read across; aluminium sulphate) - Lithium carbonate;Lithane : 96hr-LC50 = 30.3 mg/L (OECD Guideline 203, GLP), 34d-NOEC (Danio rerio) = 15.
PAGE 18
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) 201, GLP) - Carbon black : 72hr-EC50 ＞ 10000 mg/L , 72hr-NOEC > 10,000mg/L (OECD Guideline 201, GLP) - Manganese : 72hr-EC50 = 4.5 mg/L (OECD TG 201, GLP), 72hr-NOEC (Scenedesmus subspicatus) = 2.5 mg/L (OECD TG 201, GLP) 12.2. Persistence and degradability Persistence - Graphite : Low persistency (log Kow is less than 4 estimated.) (Log Kow = 0.78) - Aluminum : Low persistency (log Kow is less than 4 estimated.
PAGE 19
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) organisms (= 45.1% biodegradation was observed after 4 days) - Carbon black : carbon black is an inorganic substance and will not biodegraded by microorganisms. 12.4. Mobility in soil - Ethyl methyl carbonate : Low potency of mobility to soil. (Koc = 1.58) (40 °C)(OECD Guideline 121, GLP) - 1,3-Dioxolan-2-one : Low potency of mobility to soil. (Koc = 3.
PAGE 20
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) 14.8 Special precautions for user in case of fire : F-A in case of leakage : S-I 14.9 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Not Available 14.10 IATA Transport : the 61st edition of the IATA of Dangerous Goods Regulations PI 965Section IB 14.11 Package labels Section XV – REGULATORY INFORMATION 15.
PAGE 21
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) Substance of Roterdame Protocol : Not regulated Substance of Stockholme Protocol : Not regulated Substance of Montreal Protocol : Not regulated 15.2 Chemical safety assessment : - No chemical safety assessment has been carried out for this product by the supplier.
PAGE 22
SAMSUNG SDI Co., Ltd. Date: Jan 7th 2020 Revision no.: 01 ELG(P11P35-11-N01,3.7L1200SPA) EINECS = European Inventory of Existing Commercial chemical Substances ELINCS = European List of Notified Chemical Substances 16.3 Key literature reference and sources for data : U.S. National library of Medicine (NLM) Hazardous Substances Data Bank (HSDB) LookChem; http://www.lookchem.com/ IUCLID: http://ecb.jrc.ec.europa.eu/IUCLID-DataSheets/7631905.pdf CHRIP(Chemical Risk Information Platform) EPISUITE v4.