SDS

Coghlan’s #529, #940BP Waterproof Matches
Page 4 of 12 December 1, 2015
3. Composition
3.1 Mixture composition
Component
% (w/w)
Exposure
Limits
(ACGIH)*
LD
50
LC
50
Potassium Chlorate
CAS No
3811-04-9
EINECS No 223
-289-7
20 - 50
N/d
1870 mg/kg
(oral/rat)
>2000
mg/kg
(dermal/rabbit)
>5.1 mg/l
(inh, rat/ 4 hr)
Quartz Powder
CAS No 14808
-60-7
EINECS No 238-878-4
10 - 20
TLV-TWA:
0.025 mg/m
3
N/d
N/d
Sulphur
CAS No 7704
-34-9
EINECS No
231-722-6
5 - 10
N/d
>5000 mg/kg
(oral/rat)
>2000 mg/kg
(dermal/rabbit)
5434 mg/l
(inh, rat/ 4 hr)
Zinc Oxide
CAS No 1314
-13-2
EINECS No
215-222-5
5 - 10
TLV-TWA:
2.0 mg/m
3
TLV
-STEL:
10 mg/m
3
7950 mg/kg
(oral/mouse)
2500 mg/m3
(inh, mouse
/
4hr)
Red Phosphorus
CAS No 7723
-14-0
EINECS No
231-768-7
5 - 10
OSHA Table Z-1
Limits for air
contaminants
TWA: 0.10 mg/m
3
15,000 mg/kg
(oral/ female rat)
Dermal N/d
N/d
Gum Rosin
CAS No 8050
-09-7
EINECS No
232-475-7
1.0 – 5.0
N/d
2800 mg/kg
(oral/rat)
>2000 mg/kg
(dermal/rabbit)
N/d
Boric Acid
CAS No 10043
-35-3
EINECS No
233-139-2
0.1 – 1.0
TLV-TWA:
2.
0 mg/m
3
TLV:STEL:
6.0 mg/m
3
2660 mg/kg
(oral/rat)
Dermal N/d
N/d
Tin (IV) Oxide
CAS No
18282-10-5
EINECS No 242-159-0
0.01 – 0.1
TLV-TWA:
2.
0 mg/m
3
20,000 mg/kg
(oral/rat)
Dermal N/d
N/d
Other undisclosed ingredients and fillers
None
N/d
N/d
N/d
GHS CLASSIFICATION: FLAM SOLID, Cat 2, ACUTE TOX. ORAL, Cat 4; ACUTE TOX, INH, Cat 4; EYE DAMAGE,
Cat 2B, SKIN SENS, Cat 1, REPORD TOX, Cat 2, ACUTE AQUATIC TOX, Cat 2; CHRONIC AQUATIC TOX, Cat 2.
* ACGIH: American Conference of Governmental Industrial Hygienists. Exposure limits may vary from time to time and from one
jurisdiction to another. Check with local regulatory agency for the exposure limits in your area.
ABBREVIATION KEY: N/p: not published, N/d: not determined, N/ap: not applicable, N/av: not available
4. First Aid Measures
4.1 Description of First Aid Measures
General advice: If ingested, immediately call a POISON CONTROL CENTER, doctor or nearest
hospital for treatment advice. For burns, seek medical advice. Wash hands after handling. Do not
eat drink or smoke until washing the hands.
In case of eye contact: Immediately flush eyes with plenty of water. If irritation occurs or persists,
flush eyes with plenty of fresh water, holding eyelids open. Remove contact lenses if easy to do.
Call a physician if an irritation persists.