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Monsanto Company, Lawn & Garden Products

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Roundup® Ready-To-Use Extended Control Weed & Grass

Killer Plus Weed Preventer II

Version: 1.0 Effective date: 11/21/2006

Monsanto Company, Lawn & Garden Products

Material Safety Data Sheet

Commercial Product

1. PRODUCT AND COMPANY IDENTIFICATION

Product name

Roundup® Ready-To-Use Extended Control Weed & Grass Killer Plus Weed Preventer

EPA Reg. No.

71995-47

Product use

Herbicide

Chemical name

Not applicable.

Synonyms

None.

Company

Monsanto Company, Lawn & Garden Products, P.0. Box 418, Marysville, OH, 43041

Telephone: 1-800-246-7219

Emergency numbers

FOR CHEMICAL EMERGENCY, SPILL LEAK, FIRE, EXPOSURE, OR ACCIDENT Call CHEMTREC - Day

or Night: 1-800-424-9300 toll free in the continental U.S., Puerto Rico, Canada, or Virgin Islands. For calls

originating elsewhere: 703-527-3887 (collect calls accepted).

FOR MEDICAL EMERGENCY - Day or Night: 1-800-246-7219

2. COMPOSITION/INFORMATION ON INGREDIENTS

Active ingredient

Pelargonic and related fatty acids; {Pelargonic and related fatty acids}

Isopropylamine salt of N-(phosphonomethyl)glycine; {Isopropylamine salt of glyphosate}

Ammonium salt of 2-[4,5-dihydro-4-methyl-4-(1-methyl)-5-oxo-1H-imidazol-2-yl]-5-methyl-3-pyridinecarboxylic

acid; {Ammonium salt of imazapic}

Composition

COMPONENT CAS No. % by weight (approximate)

Pelargonic and related fatty acids 112-05-0 2

Isopropylamine salt of glyphosate 38641-94-0 1

Ammonium salt of imazapic 104098-49-9 0.017

Other ingredients 96.983

The specific chemical identity is being withheld because it is trade secret information of Monsanto Company.

OSHA Status

This product is hazardous according to the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

3. HAZARDS IDENTIFICATION

Emergency overview

Appearance and odour (colour/form/odour): Hazy - Clear / Liquid / Slight

Summary of content (10 pages)

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Monsanto Company, Lawn & Garden Products Roundup® Ready-To-Use Extended Control Weed & Grass Killer Plus Weed Preventer II Version: 1.0 Page: 1 / 10 Effective date: 11/21/2006 Monsanto Company, Lawn & Garden Products Material Safety Data Sheet Commercial Product 1. PRODUCT AND COMPANY IDENTIFICATION Product name Roundup® Ready-To-Use Extended Control Weed & Grass Killer Plus Weed Preventer II EPA Reg. No. 71995-47 Product use Herbicide Chemical name Not applicable. Synonyms None.
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Monsanto Company, Lawn & Garden Products Roundup® Ready-To-Use Extended Control Weed & Grass Killer Plus Weed Preventer II Version: 1.0 Page: 2 / 10 Effective date: 11/21/2006 CAUTION! CAUSES MODERATE EYE IRRITATION Potential health effects Likely routes of exposure Skin contact, eye contact, inhalation Eye contact, short term May cause temporary eye irritation. Skin contact, short term Not expected to produce significant adverse effects when recommended use instructions are followed.
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Monsanto Company, Lawn & Garden Products Roundup® Ready-To-Use Extended Control Weed & Grass Killer Plus Weed Preventer II Version: 1.0 Page: 3 / 10 Effective date: 11/21/2006 Fire fighting equipment Self-contained breathing apparatus. Equipment should be thoroughly decontaminated after use. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protection recommended in section 8. Environmental precautions SMALL QUANTITIES: Low environmental hazard. LARGE QUANTITIES: Minimise spread.
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Monsanto Company, Lawn & Garden Products Roundup® Ready-To-Use Extended Control Weed & Grass Killer Plus Weed Preventer II Version: 1.0 Page: 4 / 10 Effective date: 11/21/2006 Airborne exposure limits Components Pelargonic and related fatty acids Exposure Guidelines No specific occupational exposure limit has been established. Isopropylamine salt of glyphosate No specific occupational exposure limit has been established.
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Monsanto Company, Lawn & Garden Products Roundup® Ready-To-Use Extended Control Weed & Grass Killer Plus Weed Preventer II Version: 1.0 Page: 5 / 10 Effective date: 11/21/2006 This section is intended for use by toxicologists and other health professionals. Data obtained on product, similar products and on components are summarized below. Eye irritation Rabbit, 3 animals, OECD 405 test: Days to heal: 14 Moderate irritation. FIFRA category III.
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Monsanto Company, Lawn & Garden Products Roundup® Ready-To-Use Extended Control Weed & Grass Killer Plus Weed Preventer II Version: 1.
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Monsanto Company, Lawn & Garden Products Roundup® Ready-To-Use Extended Control Weed & Grass Killer Plus Weed Preventer II Version: 1.0 Page: 7 / 10 Effective date: 11/21/2006 Other effects: histopathologic effects, blood biochemistry effects Rat, oral, 2 years: NOEL tumour: 1,133 mg/kg body weight/day NOAEL toxicity: 1,133 mg/kg body weight/day Target organs/systems: none Other effects: none No tumours.
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Monsanto Company, Lawn & Garden Products Roundup® Ready-To-Use Extended Control Weed & Grass Killer Plus Weed Preventer II Version: 1.0 Page: 8 / 10 Effective date: 11/21/2006 Arthropod toxicity Honey bee (Apis mellifera): Oral, 48 hours, LR50: > 7,841 µg/bee Honey bee (Apis mellifera): Contact, 48 hours, LD50: > 1,078 µg/bee Soil organism toxicity, invertebrates Earthworm (Eisenia foetida): Acute toxicity, 14 days, LC50: > 10,000 mg/kg dry soil Practically non-toxic.
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Monsanto Company, Lawn & Garden Products Roundup® Ready-To-Use Extended Control Weed & Grass Killer Plus Weed Preventer II Version: 1.0 Page: 9 / 10 Effective date: 11/21/2006 Follow all local/regional/national/international regulations. 14. TRANSPORT INFORMATION The data provided in this section is for information only. Please apply the appropriate regulations to properly classify your shipment for transportation. Not hazardous under the applicable DOT, ICAO/IATA, IMO, TDG and Mexican regulations. 15.
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Monsanto Company, Lawn & Garden Products Roundup® Ready-To-Use Extended Control Weed & Grass Killer Plus Weed Preventer II Version: 1.0 Page: 10 / 10 Effective date: 11/21/2006 Although the information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed to be correct as of the date hereof, MONSANTO Company or any of its subsidiaries makes no representations as to the completeness or accuracy thereof.