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Safety Data Sheet

LUPRANATEM20 ISO

Revision date : 2015/10/05

Page: 1/15

Version: 5.2

(30089687/SDS_GEN_US/EN)

1. Identification

Product identifier used on the label

LUPRANATE*M20 ISO

Recommended use of the chemical and restriction on use

Recommended use*: polyurethane component; industrial chemicals

Suitable for use in industrial sector: Polymers industry; chemical industry

* The “Recommended use” identified for this product is provided solely to comply with a Federal requirement and is not part of

the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or

implied, including by incorporation into or reference in the seller's sales agreement.

Details of the supplier of the safety data sheet

Company:

BASF CORPORATION

100 Park Avenue

Florham Park, NJ 07932, USA

Telephone: +1 973 245-6000

Emergency telephone number

CHEMTREC: 1-800-424-9300

BASF HOTLINE: 1-800-832-HELP (4357)

Other means of identification

Chemical family: aromatic isocyanates

Synonyms: POLYMETHYLENE POLYPHENYLISOCYANATE

2. Hazards Identification

According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

Classification of the product

Acute Tox.

4 (Inhalation - mist)

Acute toxicity

Eye Dam./Irrit.

Serious eye damage/eye irritation

Skin Corr./Irrit.

Skin corrosion/irritation

Skin Sens.

Skin sensitization

Resp. Sens.

Respiratory sensitization

STOT SE

3 (irritating to

respiratory system)

Specific target organ toxicity — single exposure

Summary of content (22 pages)

PAGE 1
Safety Data Sheet LUPRANATEM20 ISO Revision date : 2015/10/05 Version: 5.2 Page: 1/15 (30089687/SDS_GEN_US/EN) 1.
PAGE 2
Safety Data Sheet LUPRANATEM20 ISO Revision date : 2015/10/05 Version: 5.2 STOT RE Page: 2/15 (30089687/SDS_GEN_US/EN) 2 (by inhalation) Specific target organ toxicity — repeated exposure Label elements Pictogram: Signal Word: Danger Hazard Statement: H320 H315 H332 H334 H317 H335 H373 Causes eye irritation. Causes skin irritation. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation.
PAGE 3
Safety Data Sheet LUPRANATEM20 ISO Revision date : 2015/10/05 Version: 5.2 Page: 3/15 (30089687/SDS_GEN_US/EN) No specific dangers known, if the regulations/notes for storage and handling are considered. Labeling of special preparations (GHS): CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA.
PAGE 4
Safety Data Sheet LUPRANATEM20 ISO Revision date : 2015/10/05 Version: 5.2 Page: 4/15 (30089687/SDS_GEN_US/EN) 4. First-Aid Measures Description of first aid measures General advice: Remove contaminated clothing. If inhaled: Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary. Immediate medical attention required. If on skin: Wash affected areas thoroughly with soap and water. If irritation develops, seek medical attention.
PAGE 5
Safety Data Sheet LUPRANATEM20 ISO Revision date : 2015/10/05 Version: 5.2 Page: 5/15 (30089687/SDS_GEN_US/EN) Hazards during fire-fighting: nitrous gases, fumes/smoke, isocyanate, vapour Advice for fire-fighters Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Keep containers cool by spraying with water if exposed to fire.
PAGE 6
Safety Data Sheet LUPRANATEM20 ISO Revision date : 2015/10/05 Version: 5.2 Page: 6/15 (30089687/SDS_GEN_US/EN) Further information on storage conditions: Formation of CO2 and build up of pressure possible. Keep container tightly closed and in a well-ventilated place. Outage of containers should be filled with dry inert gas at atmospheric pressure to avoid reaction with moisture. Storage stability: Storage temperature: 32 - 110 °F Protect against moisture. 8.
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Safety Data Sheet LUPRANATEM20 ISO Revision date : 2015/10/05 Version: 5.2 Page: 7/15 (30089687/SDS_GEN_US/EN) 9.
PAGE 8
Safety Data Sheet LUPRANATEM20 ISO Revision date : 2015/10/05 Version: 5.2 Page: 8/15 (30089687/SDS_GEN_US/EN) not fire-propagating Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions Reacts with water, with formation of carbon dioxide. Risk of bursting. Reacts with alcohols. Reacts with acids. Reacts with alkalies. Reacts with amines. Risk of exothermic reaction. Risk of polymerization.
PAGE 9
Safety Data Sheet LUPRANATEM20 ISO Revision date : 2015/10/05 Version: 5.2 Page: 9/15 (30089687/SDS_GEN_US/EN) An aerosol was tested. Dermal Information on: Diphenylmethane-4,4'-diisocyanate (MDI) Type of value: LD50 Species: rabbit (male/female) Value: > 9,400 mg/kg ---------------------------------Assessment other acute effects Assessment of STOT single: Causes temporary irritation of the respiratory tract.
PAGE 10
Safety Data Sheet LUPRANATEM20 ISO Revision date : 2015/10/05 Version: 5.2 Page: 10/15 (30089687/SDS_GEN_US/EN) Result: sensitizing Can cause skin sensitization other Species: guinea pig Result: sensitizing Studies in animals suggest that dermal exposure may lead to pulmonary sensitization. However, the relevance of this result for humans is unclear. ---------------------------------Aspiration Hazard No aspiration hazard expected.
PAGE 11
Safety Data Sheet LUPRANATEM20 ISO Revision date : 2015/10/05 Version: 5.2 Page: 11/15 (30089687/SDS_GEN_US/EN) Assessment of carcinogenicity: A carcinogenic potential cannot be excluded after prolonged exposure to severely irritating concentrations. These effects are not relevant to humans at occupational levels of exposure. IARC Group 3 (not classifiable as to human carcinogenicity).
PAGE 12
Safety Data Sheet LUPRANATEM20 ISO Revision date : 2015/10/05 Version: 5.2 Page: 12/15 (30089687/SDS_GEN_US/EN) 12. Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations.
PAGE 13
Safety Data Sheet LUPRANATEM20 ISO Revision date : 2015/10/05 Version: 5.2 Page: 13/15 (30089687/SDS_GEN_US/EN) Assessment transport between environmental compartments The substance will not evaporate into the atmosphere from the water surface. Adsorption to solid soil phase is not expected. 13. Disposal considerations Waste disposal of substance: Incinerate or dispose of in a licensed facility. Do not discharge substance/product into sewer system.
PAGE 14
Safety Data Sheet LUPRANATEM20 ISO Revision date : 2015/10/05 Version: 5.2 Page: 14/15 (30089687/SDS_GEN_US/EN) 87-9 Reportable Quantity for release: State regulations State RTK NJ PA 13,157.
PAGE 15
Safety Data Sheet LUPRANATEM20 ISO Revision date : 2015/10/05 Version: 5.
PAGE 16
SAFETY DATA SHEET GRA Services International 5000 E 2nd St. Edmond, OK 73034 405-330-2395 TRANSPORTATION EMERGENCY CALL CHEMTREC: 800-424-9300 INTERNATIONAL: 703-527-3887 ----------------------------------------------------------------------------------------------------------------------------1. CHEMICAL PRODUCT IDENTIFICATION: ----------------------------------------------------------------------------------------------------------------------------PRODUCT NAME ........
PAGE 17
Precautionary Statements (Response): P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P303+P352 IF ON SKIN: Wash with plenty of soap and water.
PAGE 18
-----------------------------------------------------------------------------------------------------------------------------------4. FIRST AID MEASURES: ------------------------------------------------------------------------------------------------------------------------------------FIRST AID FOR EYES: Flush with large amounts of water for at least 15 minutes, occasionally holding eyelids open with fingers to ensure that the eyes are being irrigated. Consult a physician if irritation occurs.
PAGE 19
diatomaceous earth; collect material for disposal. Wash spill area with water. -------------------------------------------------------------------------------------------------------------------------------7.
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---------------------------------------------------------------------------------------------------------------------------------10. STABILITY AND REACTIVITY: ---------------------------------------------------------------------------------------------------------------------------------STABILITY.........................................: This is a stable material. HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBILITIES.......................: Oxidizing materials and isocyanates. INSTABILITY CONDITIONS..
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IMO / IMDG CODE (OCEAN) --------------------------------------HAZARD CLASS DIVISION NUMBER: Non-Regulated ICAO / IATA (AIR) ------------------------HAZARD CLASS DIVISION NUMBER: Unknown Rating ----------------------------------------------------------------------------------------------------------------------------------15.
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