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SAMSUNG SDI Co., Ltd.

Date: January 1

2019 Revision no.: 01

MODEL INR18650-20R

Page 1 of 22

Safety Data Sheet

Regulation : In accordance with Regulation (EU) 2015/830 (REACH), Annex II, and OSHA 29 CFR

1910.1200

Section I – IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF

THE COMPANY/UNDERTAKING

Important Note: As a solid, manufactured article, exposure to hazardous ingredients is not expected with

normal use. This battery is an article pursuant to 29 CFR 1910.1200 and, as such, is not subject to the

OSHA Hazard Communication Standard requirement. The information contained in this Safety Data Sheet

contains valuable information critical to the safe handling and proper use of the product. This SDS should be

retained and available for employees and other users of this product.

1.1 Product identifier

Substance name : INR18650-20R

Synonyms :

Lithium-ion Cell, Lithium-ion Pack, Lithium-ion Battery, Li-Ion Cell, Li-Ion Pack, Li-Ion Battery

1.2 Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses : Lithium-ion batteries

Uses advised against : Use for recommended use only

Further Information : Not available

1.3 Details of the supplier of the safety data sheet

Supplier : SAMSUNG SDI Co., Ltd.

Street address/P.O. Box : 150-20, Gongse-ro, Giheung-gu, Yongin-si, Gyeonggi-do, Korea

Country ID/Postcode/Place :

Telephone number : 1-800-424-9300: US and Canada / 1-703-527-3887: International

Responsible Department: Quality team

e-mail address of competent person responsible for the SDS : Not available

National contact : 1-800-424-9300: US and Canada / 1-703-527-3887: International

1.4 Emergency Telephone

: 1-800-424-9300: US and Canada / 1-703-527-3887: International

Opening hours : Not available

Other comments : Not available

1.5 Further Information

Battery-System: Lithium-ion (Li-ion)

Nominal Voltage: 3.6 V

Rated Capacity: 2.0 Ah

Wh rating: 7.2 Wh

Anode (negative electrode): based on intercalation graphite

Cathode (positive electrode): based on lithiated metal oxide (Cobalt, Nickel or Manganese)

Remark:

Summary of content (22 pages)

PAGE 1
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R Safety Data Sheet Regulation : In accordance with Regulation (EU) 2015/830 (REACH), Annex II, and OSHA 29 CFR 1910.1200 Section I – IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Important Note: As a solid, manufactured article, exposure to hazardous ingredients is not expected with normal use. This battery is an article pursuant to 29 CFR 1910.
PAGE 2
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation. SAMSUNG SDI Co., Ltd. makes no warranty, expressed or implied, with respect to this information and disclaims all liabilities from reliance on it.
PAGE 3
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R 2.3 Other hazards : Appearance, Color and Odor: Solid object with no odor. Primary Routes(s) of Exposure: These chemicals are contained in a sealed enclosure. Risk of exposure occurs only if the cell or pack is mechanically, thermally, electrically or physically abused to the point of compromising the enclosure.
PAGE 4
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R 12190-79-3 235-362-0 - 1~10 cobalt lithium dioxide 7440-50-8 231-159-6 - 1~10 Copper 616-38-6 210-478-4 - 1~10 dimethyl carbonate 7429-90-5 231-072-3 - 1~10 Aluminium 9002-88-4 Not available - 1~10 Polyethylene 96-49-1 202-510-0 - 1~10 1,3-Dioxolan-2-one 21324-40-3 244-334-7 - 1~10 lithium hexafluorophosphate(1-) 141-78-6 205-500-4 - 0.1~1 ethyl acetate 1333-86-4 215-609-9 - 0.
PAGE 5
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - In case of inhalation of organic electrolyte mist, remove from exposure to fresh air. - If necessary give oxygen. Get medical attention. Following ingestion : - In case of ingestion of electrolyte don’t induce vomiting. - If patient is conscious and alert give 2~4 cupfuls of milk or water. - Never give anything by mouth to an unconscious person. - Get medical attention immediately.
PAGE 6
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment : Use personal protective equipment, see Section 8 Emergency procedures : - In case of cell damage, possible release of dangerous substances and a flammable gas mixture. - Eliminate all ignition sources. - Please note that materials and conditions to avoid.
PAGE 7
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - Storage at room temperature (approx. 20℃) at approx. 40% of the nominal capacity - Keep in closed original container. 7.3 Specific end use(s) Recommendations : Not available Industrial sector specific solutions : Not available Section VIII – EXPOSURE CONTROLS / PERSONAL PROTECTION 8.
PAGE 8
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R Copper TWA = 0.
PAGE 9
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R compounds (as Ni)) lithium carbonate 1-Methyl-2-pyrrolidinone Not applicable Not applicable 0.015 mg/m3 (soluble compounds (as Ni)) Not applicable Not available Not applicable Not applicable Not available TWA = 40 mg/m³, TWA= 10 Not applicable Not applicable ppm, STEL = 80 mg/m³, STEL = 20 ppm 8.2 Exposure controls 8.2.
PAGE 10
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - Discard contaminated work clothing after one work day. Respiratory protection : - None required during normal use. - Wear NIOSH or European Standard EN 149 approved full or half face piece (with goggles) respiratory protective equipment when necessary. - In lack of oxygen(< 19.5%), wear the supplied-air respirator or self-contained oxygen breathing apparatus.
PAGE 11
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R Explosive properties : Not available Oxidizing properties : Not available Molecular weight : Not available 9.2 Other information Not available Section X – STABILITY AND REACTIVITY 10.1 Reactivity - Stable at ambient temperature. 10.2 Chemical stability - There is no hazard when the measures for handling and storage are followed. - Stable under normal temperatures and pressures. 10.
PAGE 12
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R Section XI – TOXICOLOGICAL INFORMATION ※ This is a product that fulfills a certain function in solid state with specific shape without discharging any chemical substance in its use and has no obligation to write (M)SDS.
PAGE 13
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - Copper : In test on skin irritation with rabbits, skin irritations were not observed. (OECD TG 404, GLP) - Dimethyl carbonate : In the skin irritation test using rabbits, the test material was not irritating. (OECD Guideline 404) - Aluminum : Aluminium oxide caused slight erythema in 2/12 rabbits. The observed effects do not lead to a classification.
PAGE 14
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - Copper : In maximization test on skin sensitization with guinea pig, skin sensitization was not observed. (OECD TG 406, GLP) - Dimethyl carbonate : In the skin sensitization test using guinea pig, this material was not skin sensitizing. (OECD Guideline 406, GLP) - Aluminum : In test with guinea pigs, it can be concluded that aluminium oxide has no sensitisation potential under the experimental conditions.
PAGE 15
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - Fe : In mammalian cell gene mutation assay electrolytic iron, positive carbonyl iron exhibited a cytotoxic and mutagenic response (OECD TG 476) - Copper : Negative reactions were observed in both in vitro(Ames test) and in vivo(DNA damage and/or repair; unscheduled DNA synthesis, micronucleus assay).
PAGE 16
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R GLP) - Carbon black : No effect on endothelins or blood pressure was observed after exposure to carbon black. There were also no effects on body temperature and activity of the animals. - Nickel; Raney nickel : In the acute oral toxicity using rat, there were no effects on clinical signs, systemic toxicity.
PAGE 17
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - Lithium hexafluorophosphate(1-) : 96hr-LC50 = 51 ~ 193 mg/L Information on major hydrolysis product of the registered substance (released rapidly on contact with water/moisture); 21d-NOEC = 4 mg F-/L - Ethyl acetate : 96hr-LC50 = 230 mg/L - Carbon black : 96hr-LC0 = 1000 mg/L (OECD TG 203, GLP) - Lithium carbonate;Lithane : 96hr-LC50 = 30.3 mg/L (OECD Guideline 203, GLP), 34d-NOEC (Danio rerio) = 15.
PAGE 18
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - Copper : Bioaccumulation is expected to be low according to the BCF < 500 (BCF = 0.02 ~ 20) - Dimethyl carbonate : Bioaccumulation is expected to be low according to the BCF < 500 (BCF = 3.2) - Aluminum : Bioaccumulation is expected to be low according to the BCF < 500 (BCF = 3.162) (estimated) - 1,3-Dioxolan-2-one : Bioaccumulation is expected to be low according to the BCF < 500 (BCF = 3.
PAGE 19
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R Section XIV – TRANSPORTATION INFORMATION ※ If those lithium-ion batteries are packed with or contained in an equipment, then it is the responsibility of the shipper to ensure that the consignment are packed in compliance to the latest edition of the IATA Dangerous Goods Regulations section Ⅱ of either Packing Instruction 966 or 967 in order for that consignment to be declared as NOT RESTRICTED (non-hazardous/non-Dangerous).
PAGE 20
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R - 1-Methyl-2-pyrrolidinone : Regulated Foreign Regulatory Information External information : U.S.A management information (OSHA Regulation) : Not regulated U.S.A management information (CERCLA Regulation) : - Copper : 5,000 lb - ethyl acetate : 5,000 lb - Nickel : 100 lb U.S.A management information (EPCRA 302 Regulation) : Not regulated U.S.A management information (EPCRA 304 Regulation) : Not regulated U.S.
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SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.
PAGE 22
SAMSUNG SDI Co., Ltd. Date: January 1st 2019 Revision no.: 01 MODEL INR18650-20R 16.4 Classification and procedure used to derive the classification for mixtures according to Regulation(EC) 1272/2008(CLP) : Not classified 16.5 Relevant H-statements : Not applicable 16.6 Training advice : - Do not handle until all safety precautions have been read and understood. 16.