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ManualsBrandsSpectracide ManualsGarden Center13 oz. Pruning Seal Waterproof Outdoor Sealant Aerosol (6-Pack)

SafetyDataSheet

SpectracidePruningSeal

Page1of17

July29,2020

ProductIdentifier: SpectracidePruningSeal

OtherMeansofIdentification:

ProductCode HG‐59000;HG‐69000

FormulaNumber 21‐1677

RecommendedUse: PruningSeal

RecommendedRestrictions: Useinaccordancewithlabeldirections

Manufacturer/Importer/Supplier/DistributorInformation:

CompanyName SpectrumGroup,DivisionofUnitedIndustriesCorporation

Address POBox142642,St.Louis,MO63114‐0642

TelephoneNumber 1‐800‐917‐5438

EmergencyTelephoneNumber:

CHEMTREC (800)424‐9300

Medical (866)823‐2749

ClassificationofSubstanceorMixture:

PhysicalHazard(s)

HealthHazard(s)

EnvironmentalHazard(s) Acutehazardstotheaquaticenvironment‐Category3

LabelElements:

HazardPictogram(s)

SignalWord

HazardStatements:

Containsgasesunderpressure;mayexplodeifheated.

Maycausecancer.

Suspectedofdamagingfertilityortheunbornchild.

Harmfultoaquaticlifewithlonglastingeffects.

Extremelyflammableaerosol.

Causesskinirritation.

PrecautionaryStatements: Keepawayfromheat,sparks,openflames,andhotsurfaces.‐No

smoking.Donotsprayonanopenflameorotherignitionsource.

Pressurizedcontainer:Donotpierceorburn,evenafteruse.

Protectfromsunlight.Donotexposetotemperaturesexceeding

50°C/122°F.Storeinawell‐ventilatedplace.

Washhandsthoroughlyafterhandling.Wearprotectivegloves.

Carcinogenicity‐Category1A

ToxictoReproduction‐Category2

Chronichazardstotheaquaticenvironment‐Category3

Danger

ConformstoHazardCommunicationStandard29CFR1910.1200

Section1‐IDENTIFICATION

Section2‐HAZARD(S)IDENTIFICATION

FlammableAerosol‐Category1

Gasesunderpressure‐Liquefiedgas

SkinIrritant‐Category2

Summary of content (17 pages)

PAGE 1
Safety Data Sheet Spectracide Pruning Seal Page 1 of 17 July 29, 2020 Conforms to Hazard Communication Standard 29 CFR 1910.
PAGE 2
Safety Data Sheet Spectracide Pruning Seal Page 2 of 17 July 29, 2020 If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice. Take off contaminated clothing and wash it before reuse. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. If exposed or concerned: Get medical advice/attention. Store locked up.
PAGE 3
Safety Data Sheet Spectracide Pruning Seal Most Important Symptoms/Effects, Acute and Delayed: Indication of Immediate Medical Attention & Special Treatment Needed: Page 3 of 17 July 29, 2020 No data available. No data available. Section 5 ‐ FIRE‐FIGHTING MEASURES General Fire Hazards: Use water spray to keep fire‐exposed containers cool. Fight fire from a protected location. Move containers from fire area. If you can do so without risk.
PAGE 4
Safety Data Sheet Spectracide Pruning Seal Page 4 of 17 July 29, 2020 Store locked up. Pressurized container: protect from sunlight and do not Conditions for Safe Storage, Including any Incompatibilities: expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. NFPA 30B Classification: Level 1 Aerosol Section 8 ‐ EXPOSURE CONTROLS / PERSONAL PROTECTION Control Parameters: Occupational Exposure Limits Chemical Identity Asphalt ‐ Fume. Asphalt ‐ Inhalable fume.
PAGE 5
Safety Data Sheet Spectracide Pruning Seal Page 5 of 17 July 29, 2020 TWA 1,000 ppm REL 800 ppm STEL 1,000 ppm TWA 800 ppm Talc (Mg3H2(SiO3)4)‐ Respirable TWA fraction. 2 mg/m3 Talc (Mg3H2(SiO3)4)‐ Respirable. REL 2 mg/m3 Talc (Mg3H2(SiO3)4)‐ Respirable TWA dust. 2 mg/m3 Talc (Mg3H2(SiO3)4) TWA 20 millions of particles per cubic foot of air Talc (Mg3H2(SiO3)4)‐ Respirable. TWA 2.4 millions of particles per cubic foot of air Butane TWA 0.1 mg/m3 Kaolin ‐ Respirable fraction.
PAGE 6
Safety Data Sheet Spectracide Pruning Seal Page 6 of 17 July 29, 2020 Kaolin ‐ Respirable fraction. TWA Kaolin ‐ Total dust. TWA TWA Kaolin ‐ Respirable fraction. TWA Kaolin ‐ Total dust. TWA Kaolin ‐ Respirable fraction. TWA TWA Kaolin ‐ Total dust. TWA 2‐Propanone STEL PEL TWA TWA STEL REL Titanium oxide (TiO2) TWA 5 mg/m3 US. OSHA Table Z‐1‐A (29 CFR 1910.1000) (1989) 10 mg/m3 US. OSHA Table Z‐1‐A (29 CFR 1910.1000) (1989) 15 mg/m3 US. OSHA Table Z‐1‐A (29 CFR 1910.
PAGE 7
Safety Data Sheet Spectracide Pruning Seal Titanium oxide (TiO2) ‐ Total dust. Page 7 of 17 July 29, 2020 TWA PEL Titanium oxide (TiO2) ‐ Respirable fraction. TWA TWA Titanium oxide (TiO2) ‐ Total dust. TWA TWA Quartz (SiO2) ‐ Respirable dust. REL Quartz (SiO2) ‐ Respirable. TWA TWA Quartz (SiO2) ‐ Respirable fraction. TWA Quartz (SiO2) ‐ Respirable dust. TWA Quartz (SiO2) ‐ Respirable dust. TWA Quartz (SiO2) ‐ Respirable dust. PEL 10 mg/m3 US. OSHA Table Z‐1‐A (29 CFR 1910.
PAGE 8
Safety Data Sheet Spectracide Pruning Seal Page 8 of 17 July 29, 2020 Quartz (SiO2) ‐ Respirable dust. OSHA_AC T Biological Limit Values Chemical Identity Benzene, methyl‐ (toluene: Sampling time: End of shift.) Benzene, methyl‐ (o‐Cresol, with hydrolysis: Sampling time: End of shift.) Benzene, methyl‐ (toluene: Sampling time: Prior to last shift of work week.) 2‐Propanone (acetone: Sampling time: End of shift.) Appropriate Engineering Controls: 0.025 mg/m3 US.
PAGE 9
Safety Data Sheet Spectracide Pruning Seal Initial boiling point and range: Flashpoint: Evaporation Rate: Flammability (solid, gas): Upper/lower flammability or explosive limits: Vapor pressure: Vapor density: Relative density: Solubility(ies): Partition coefficient (n‐ octanol/water): Auto‐ignition temperature: Decomposition temperature: Viscosity: Heat of Combustion: Page 9 of 17 July 29, 2020 No data available No data available No data available No data available No data available No data available No d
PAGE 10
Safety Data Sheet Spectracide Pruning Seal 2‐Propanone Titanium oxide (TiO2) Quartz (SiO2) Page 10 of 17 July 29, 2020 LD50 (Rat): 5,580 mg/kg LD50 (Rat): >5,000 mg/kg LD50: >5,000 mg/kg DERMAL: Product: Not classified for acute toxicity based on available data.
PAGE 11
Safety Data Sheet Spectracide Pruning Seal Propane Butane 2‐Propanone Titanium oxide (TiO2) Page 11 of 17 July 29, 2020 NOAEL (Rat(Female, Male), Inhalation): 625 ppm(m) Inhalation Experimental Result, Key study NOAEL (Rat(Female, Male), Inhalation ‐ vapor): 2,355 mg/l Inhalation Experimental Result, Key study NOAEL (Rat(Female, Male), Inhalation ≥28d): 4,000ppm(m) Inhalation Experimental Result, Key study LOAEL (Rat(Female, Male), Inhalation ≥28d): 12,000ppm(m) Inhalation Experimental Result, Key study
PAGE 12
Safety Data Sheet Spectracide Pruning Seal Page 12 of 17 July 29, 2020 Asphalt Overall evaluation: 2B. Possibly carcinogenic to humans. Talc (Mg3H2(SiO3)4) Overall evaluation: 3. Not classifiable as to carcinogenicity to humans. Quartz (SiO2) Overall evaluation: 1. Carcinogenic to humans. US. National Toxicology Program (NTP) Report to Carcinogens: Quartz (SiO2) Known to Be Human Carcinogen US. OSHA Specifically Regulated Substances (29 CFR 1910.
PAGE 13
Safety Data Sheet Spectracide Pruning Seal Propane Butane 2‐Propanone Titanium oxide (TiO2) Page 13 of 17 July 29, 2020 LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study LC 50 (Oncorhynchus mykiss, 96 h): 5,540 mg/l Experimental result, Key study LC 50 (Oncorhynchus mykiss, 96 h): > 100 mg/l Experimental result, Weight of Evidence study Aquatic Invertebrates: Product: No data available.
PAGE 14
Safety Data Sheet Spectracide Pruning Seal Page 14 of 17 July 29, 2020 Leuciscus idus, Bioconcentration Factor (BCF): 90 Aquatic sediment Experimental result, Key study Haddock, adult, Bioconcentration Factor (BCF): 0.
PAGE 15
Safety Data Sheet Spectracide Pruning Seal Page 15 of 17 July 29, 2020 Limited Quantity: Marine Pollutant: ≤1L No Section 15 ‐ REGULATORY INFORMATION US Federal Regulations Restrictions on use: Not known. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) US. OSHA Specifically Regulated Substances (29 CFR 1910.1001‐1050) Chemical Identity Quartz (SiO2) OSHA hazard(s) lung effects immune system effects Cancer kidney effects CERCLA Hazardous Substance List (40 CFR 302.
PAGE 16
Safety Data Sheet Spectracide Pruning Seal Page 16 of 17 July 29, 2020 SARA 311/312 Hazardous Chemical Chemical Identity Threshold Planning Quantity Asphalt 10000 lbs Benzene, methyl‐ 10000 lbs Propane 10000 lbs Butane 10000 lbs Talc (Mg3H2(SiO3)4) 10000 lbs Kaolin 10000 lbs 2‐Propanone 10000 lbs Titanium oxide (TiO2) 10000 lbs Quartz (SiO2) 10000 lbs SARA 313 (TRI Reporting) Chemical Identity Benzene, methyl‐ Reporting threshold for other users lbs Threshold Planning Quantity lbs Clean Air Act (CAA) S
PAGE 17
Safety Data Sheet Spectracide Pruning Seal Page 17 of 17 July 29, 2020 Talc (Mg3H2(SiO3)4) Kaolin 2‐Propanone US. Rhode Island RTK No ingredient regulated by RI Right‐to‐Know Law present. Inventory Status: US TSCA Inventory: Disclaimer: On or in compliance with the inventory Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated.