SDS

STANLEY CHALKS SDS
STANLEY CHALKS SDS
PAGE 4 OF 11
8. EXPOSURE CONTROLS - PERSONAL PROTECTION (Continued)
EXPOSURE LIMITS/CONTROL PARAMETERS (continued):
WORKPLACE EXPOSURE LIMITS/CONTROL PARAMETERS (continued):
CHEMICAL
NAME
CAS #
EXPOSURE LIMITS IN AIR
ACGIH-TLVs
OSHA-PELs
NIOSH-RELs
NIOSH
OTHER
TWA
STEL
TWA
STEL
TWA
STEL
IDLH
mg/m
3
mg/m
3
mg/m
3
mg/m
3
mg/m
3
mg/m
3
mg/m
3
mg/m
3
Calcium
Carbonate
1317-65-3
NE
NE
15 (total dust); 5
(resp. fract.)
NE
10 (total dust);
5 (resp. fract.)
NE
NE
NE
Carbon Black
1333-86-4
3
(inhal.
fract.)
NE
3.5
NE
3.5 (0.1 in
presence of
PAHs, as
PAHs; 10-hr
TWA)
NE
1750
DFG MAK: as Inhalable Dust
Carcinogen: IARC-2B, MAK-
3B, NIOSH-Ca (in presence
of PAHs), TLV-A3
C.I. Pigment
Blue 29
57455-37-5
NE
NE
NE
NE
NE
NE
NE
NE
Crystalline Silica
14808-60-7
0.025
(resp.
fract.)
NE
30 mg/m
3
(total dust)
% SO
2
+ 2
0.05 (resp.
dust)
NE
0.05
Carcinogen: IARC-1, MAK-1
(respirable), NIOSH-Ca,
NTP-K (respirable), TLV-A2
250 mppcf (resp. dust)
% SiO2 + 5
or
10 mg/m
3
(resp. dust)
% SO
2
+ 2
Iron
Oxide/Hematite
Exposure Limits
given are for
Iron oxide CAS#
1309-37-1
1317-60-8
3 (resp.
fract.)
NE
10 (fume)
NE
5 (dust and
fume as Fe)
NE
NE
DFG MAK: With the exception
of iron oxides which are not
biologically available.
Carcinogen: IARC-3, MAK-
3B, TLV-A4
Magnesium
Carbonate
Exposure limits
given are for
talc, containing
no asbestos
fibers, CAS #
14807-96-6)
546-93-0
2 (resp.
fract.)
NE
20 mppcf (containing
< 1% quartz)
NE
2 (resp. dust) &
< 1% quartz
NE
NE
Carcinogen: IARC-3, MAK-
3B, TLV-A4 (respirable)
NE = Not Established. See Section 16 for Definitions of Terms Used.
INTERNATIONAL OCCUPATIONAL EXPOSURE LIMITS: Currently, the following additional international exposure limits are
established for some components of this product.
CALCIUM CARBONATE:
Belgium: TWA = 10 mg/m
3
, MAR 2002
Hungary: TWA = 10 mg/m
3
, SEP 2000
Japan: OEL = 2 mg/m
3
(resp. dust), 84 mg/m
3
(total
dust), MAY 2009
Korea: TWA = 10 mg/m
3
, 2006
Mexico: TWA = 10 mg/m
3
; STEL 20 mg/m
3
(inhalable), 2004
The Netherlands: MAC-TGG = 10 mg/m
3
, 2003
New Zealand: TWA = 10 mg/m
3
(inspirable dust), JAN
2002
Poland: MAC(TWA) dust = 10 mg/m
3
, JAN 1999
Russia: STEL = 6 mg/m
3
, JUN 2003
Switzerland: MAK-W = 3 mg/m
3
, DEC 2006
United Kingdom: TWA = 10 mg/m
3
(inhal. dust), OCT
2007
United Kingdom: TWA = 4 mg/m
3
(respirable dust),
OCT 2007
In Argentina, Bulgaria, Colombia, Jordan, Singapore,
Vietnam check ACGIH TLV
CARBON BLACK:
Australia: TWA = 2.5 mg/m
3
, JUL 2008
Austria: MAK-TMW = 2 mg/m
3
, resp, 2007
Belgium: TWA = 2 mg/m
3
, MAR 2002
Denmark: TWA = 0.3 f/cc, carc, MAY 2011
Finland: TWA 0.5 mg/m
3
, NOV 2011
France: VME = 3.5 mg/m
3
, FEB 2006
Iceland: TWA = 0.3 f/cc, NOV 2011
Japan: OEL = 0.5 mg/m
3
(resp. dust), 2 mg/m
3
(total
dust), MAY 2009
Korea: TWA = 2 mg/m
3
, 2006
CARBON BLACK (continued):
Mexico: TWA = 2 mg/m
3
; STEL = 7 mg/m
3
, 2004
The Netherlands: MAC-TGG = 1 mg/m
3
, 2003
New Zealand: TWA = 2 mg/m
3
(respirable dust), JAN 2002
Norway: TWA = 3.5 mg/m3, JAN 1999
Peru: TWA = 2 mg/m
3
, JUL 2005
The Philippines: TWA = 3.5 mg/m
3
, JAN 1993
Russia: STEL = 4 mg/m
3
, JUN 2003
Sweden: TWA = 2 mg/cm
3
(total dust); TWA = 1 mg/cm
3
(resp. dust), JUN 2005
Switzerland: MAK-W = 2 mg/m
3
, DEC 2006
United Kingdom: TWA = 1 mg/m
3
(resp. dust), OCT 2007
In Argentina, Bulgaria, Colombia, Jordan, Singapore,
Vietnam check ACGIH TLV
CRYSTALLINE SILICA:
Australia: TWA = 0.1 mg/m
3
, JUL 2008
Belgium: TWA = 0.1 mg/m
3
(resp. dust), MAR 2002
Denmark: TWA = 0.1 mg/m
3
(respirable), carc, MAY 2011
Denmark: TWA = 0.1 mg/m
3
(resp.), carc, MAY2011
Denmark: TWA = 0.3 mg/m
3
(total), MAY 2011
Finland: TWA = 0.05 mg/m
3
, resp. dust, SEP 2009
France: VME = 0.1 mg/m
3
, (resp), FEB 2006
Iceland: TWA = 0.1 mg/m
3
(resp. dust), NOV 2011
Japan: OEL-C = 0.03 mg/m
3
(respirable), APR 2007
Korea: TWA = 0.1 mg/m
3
, 2006
Mexico: TWA = 0.1 mg/m
3
(respirable), 2004
The Netherlands: MAC-TGG = 0.075 mg/m
3
, 2003
New Zealand: TWA = 0.2 mg/m
3
(respirable dust), JAN
2002
Norway: TWA = 0.1 mg/m
3
(resp. dust), JAN 1999
CRYSTALLINE SILICA (continued):
Norway: TWA = 0.3 mg/m
3
(total dust), JAN 1999
Peru: TWA = 0.05 mg/m
3
, JUL 2005
Russia: TWA = 1 mg/m
3
, STEL = 3 mg/m
3
, JUN 2003
Sweden: TWA = 0.1 mg/m
3
(resp. dust), JUN 2005
Switzerland: MAK-W = 0.15 mg/m
3
, DEC 2006
Thailand: TWA = 10 mg/m
3
(resp. dust), JAN 1993
Thailand: TWA = 30 mg/m
3
(total dust), JAN 1993
United Kingdom: TWA = 0.1 mg/m
3
(resp. dust), OCT 2007
In Argentina, Bulgaria, Colombia, Jordan, Singapore,
Vietnam check ACGIH TLV
IRON OXIDE/MAGNETITE:
Russia: STEL = 4 mg/m
3
, JUN 2003
MAGNESIUM CARBONATE (TALC):
Australia: TWA = 2.5 mg(F)/m
3
, JUL 2008
Belgium: TWA = 10 mg/m
3
, MAR 2002
France: VME = 10 mg/m
3
, FEB 2006
Korea: TWA = 10 mg/m
3
, 2006
Mexico: TWA = 10 mg/m
3
; STEL = 20 mg/m
3
(inhalable),
2004
The Netherlands: MAC-TGG = 10 mg/m
3
, 2003
New Zealand: TWA = 10 mg/m
3
(inspirable dust), JAN2002
Norway: TWA = 0.6 mg(F)/m
3
, JAN 1999
Peru: TWA = 10 mg/m
3
, JUL 2005
Russia: STEL = 10 mg/m
3
, JUN 2003
Switzerland: MAK-W = 3 mg/m
3
, DEC 2006
United Kingdom: TWA = 4 mg/m
3
(resp. dust), OCT 2007
United Kingdom: TWA = 10 mg/m
3
(inhal. dust), OCT 2007
In Argentina, Bulgaria, Colombia, Jordan, Singapore,
Vietnam check ACGIH TLV
PROTECTIVE EQUIPMENT: The following information on appropriate Personal Protective Equipment is provided to
assist employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132, including U.S.
Federal OSHA Respiratory Protection (29 CFR 1910.134), OSHA Eye Protection 29 CFR 1910.133, OSHA Hand
Protection 29 CFR 1910.138, OSHA Foot Protection 29 CFR 1910.136 and OSHA Body Protection 29 CFR1910.132),
equivalent standards of Canada (including CSA Respiratory Standard Z94.4-02, Z94.3-M1982, Industrial Eye and Face
Protectors and CSA Standard Z195-02, Protective Footwear), or standards of EU member states (including EN 529:2005
for respiratory PPE, CEN/TR 15419:2006 for hand protection, and CR 13464:1999 for face/eye protection). Please
reference applicable regulations and standards for relevant details.