SDS

STANLEY CHALKS SDS
STANLEY CHALKS SDS
PAGE 9 OF 11
16. OTHER INFORMATION (Continued)
ANSI LABELING (continued)): FIRST-AID: In case of contact, flush skin or eyes with plenty of water. If inhaled, remove to
fresh air. If ingested do not induce vomiting. Get medical attention if adverse effects continue after exposure ends. IN
CASE OF FIRE: Use water fog, dry chemical, CO
2
, or “alcohol” foam. IN CASE OF SPILL: Sweep up spill, avoiding the
generation of airborne dusts. Place residual in appropriate container and seal. Consult Safety Data Sheet for additional
information.
GLOBAL HARMONIZATION LABELING AND CLASSIFICATION: Classified in accordance with CLP Regulation (EC)
1272/2008.
Classification: Carcinogenic Cat. 2
Signal Word: Warning
Hazard Statements: H351: Suspected of causing cancer. For Blue Chalk Only: EUH032: Contact with acids liberates very toxic gas
(hydrogen sulfide).
Precautionary Statements:
Prevention: P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and
understood. P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response: P308 + P313: IF exposed or concerned: Get medical advice/attention.
Storage: P405: Store locked up.
Disposal: P501: Dispose of contents/containers in accordance with all local, regional, national and international regulations.
Hazard Symbol/Pictograms: GHS08
EU 67/548/EEC LABELING AND CLASSIFICATION: Classified in accordance with the European Community Council
Directive 67/548/EEC or subsequent Directives.
Classification: Carcinogenic Cat. 3
Risk Phrases: R45: May cause cancer. For Blue Chalk Only: R32: Contact with acids liberates very toxic gas (hydrogen sulfide).
Safety Phrases: S(1/2): Keep locked up and out of the reach of children. (Can be omitted when product is for industrial use only). S22:
Do not breathe dust. S25: Avoid contact with eyes. S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S38: In case of insufficient ventilation wear suitable respiratory equipment. S45: In case of accident or if you feel unwell seek
medical advice immediately (show the label where possible). S53: Avoid exposure - obtain special instructions before use.
Hazard Symbol: Xn
CLASSIFICATION FOR COMPONENTS:
Full Text Global Harmonization AND EU CLP Regulation (EC) 1272/2008:
Crystalline Silica: This is a self-classification.
Classification: Carcinogenic Category 2
Hazard Statement Codes: H351: Suspected of causing cancer.
C.I. Pigment Blue 29: This is a self-classification.
Classification: None.
Hazard Statement Codes: EUH032: Contact with acids liberates very toxic gas (hydrogen sulfide).
All Other Components: No classification has been published or is applicable.
Full Text EU 67/548/EEC:
Crystalline Silica: This is a self-classification.
Classification: Carcinogenic Category 3
Risk Phrases: R45: May cause cancer.
Crystalline Silica: This is a self-classification.
Classification: None.
Risk Phrases: R32: Contact with acids liberates very toxic gas (hydrogen sulfide).
All Other Components: No classification has been published or is applicable.
PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc.
PO Box 1961, Hilo, HI 96721 [phone]
DATE OF PRINTING: November 25, 2013
REVISION INFORMATION: July 2010: Review of SDS and up-date. Format up-dated. Section 3 EU Crystalline Silica self-
classification added. Section 8 Exposure limits up-dated. Section 11 Cancer ratings up-dated. Section 15
EU component classification added. July 2013: Review and revise entire SDS to add GHS compliance.
Up-date Section 8 Exposure Limits. Section 11 Cancer ratings up-dated.
The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use
thereof. Stanley Works assumes no responsibility for injury to the vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data
sheet. Additionally, Stanley Works assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed.
Furthermore, vendee assumes the risk in his use of the material.
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on an SDS. Some of these, which are commonly used, include the following:
CAS #: This is the Chemical Abstract Service Number that uniquely identifies each
constituent.
EXPOSURE LIMITS IN AIR:
CEILING LEVEL: The concentration that shall not be exceeded during any part of the working
exposure.
DFG MAK Germ Cell Mutagen Categories: 1: Germ cell mutagens which have been shown
to increase the mutant frequency in the progeny of exposed humans. 2: Germ cell mutagens
which have been shown to increase the mutant frequency in the progeny of exposed
mammals. 3A: Substances which have been shown to induce genetic damage in germ cells
of human of animals, or which produce mutagenic effects in somatic cells of mammals in vivo
and have been shown to reach the germ cells in an active form.
EXPOSURE LIMITS IN AIR (continued):
DFG MAK Germ Cell Mutagen Categories (continued): 3B: Substances which are
suspected of being germ cell mutagens because of their genotoxic effects in mammalian
somatic cell in vivo; in exceptional cases, substances for which there are no in vivo data, but
which are clearly mutagenic in vitro and structurally related to known in vivo mutagens. 4: Not
applicable (Category 4 carcinogenic substances are those with non-genotoxic mechanisms of
action. By definition, germ cell mutagens are genotoxic. Therefore, a Category 4 for germ cell
mutagens cannot apply. At some time in the future, it is conceivable that a Category 4 could
be established for genotoxic substances with primary targets other than DNA [e.g. purely
aneugenic substances] if research results make this seem sensible.) 5: Germ cell mutagens,
the potency of which is considered to be so low that, provided the MAK value is observed,
their contribution to genetic risk for humans is expected not to be significant.