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VIAL FLUID 2 (360 Vials)

VIAL FLUID 2 (360 Vials) MSDS

PAGE 8 OF 9

DEFINITIONS OF TERMS (Continued)

HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD

RATINGS (continued):

PHYSICAL HAZARD (continued)

2 (continued): Unstable Reactives: Substances that may polymerize, decompose,

condense, or self-react at ambient temperature and/or pressure, but have a low

potential for significant heat generation or explosion. Substances that readily form

peroxides upon exposure to air or oxygen at room temperature);3 (Water Reactivity:

Materials that may form explosive reactions with water. Organic Peroxides: Materials

that are capable of detonation or explosive reaction, but require a strong initiating

source, or must be heated under confinement before initiation; or materials that react

explosively with water. Explosives: Division 1.2 – Explosive substances that have a fire

hazard and either a minor blast hazard or a minor projection hazard or both, but do not

have a mass explosion hazard. Compressed Gases: Pressure >

514.7 psi absolute at

21.1°C (70°F) [500 psig]. Pyrophorics: No Rating. Oxidizers: Packing Group I Solids

any material that, in either concentration tested, exhibits a mean burning time less than

the mean burning time of a 3.:2 potassium bromate/cellulose mixture. Liquids

: Any

material that spontaneously ignites when mixed with cellulose in a 1:1 ratio, or which

exhibits a mean pressure rise time less than the pressure rise time of a 1:1 perchloric

acid (50%)/cellulose mixture. Unstable Reactives: Substances that may polymerize,

decompose, condense or self-react at ambient temperature and/or pressure and have

a moderate potential to cause significant heat generation or explosion.); 4 (Water

Reactivity: Materials that react explosively with water without requiring heat or

confinement. Organic Peroxides: Materials that are readily capable of detonation or

explosive decomposition at normal temperature and pressures. Explosives: Division

1.1 & 1.2-explosive substances that have a mass explosion hazard or have a projection

hazard. A mass explosion is one that affects almost the entire load instantaneously.

Compressed Gases: No Rating. Pyrophorics: Add to the definition of Flammability “4”.

Oxidizers: No “4” rating. Unstable Reactives: Substances that may polymerize,

decompose, condense or self-react at ambient temperature and/or pressure and have

a high potential to cause significant heat generation or explosion.).

NATIONAL FIRE PROTECTION ASSOCIATION HAZARD RATINGS:

HEALTH HAZARD: 0 (materials that, under emergency conditions, would offer no

hazard beyond that of ordinary combustible materials): Gases and vapors whose LC

for acute inhalation toxicity is greater than 10,000 ppm. Dusts and mists whose LC

for acute inhalation toxicity is greater than 200 mg/L. Materials whose LD

for acute

dermal toxicity is greater than 2000 mg/kg. Materials whose LD

for acute oral

toxicity is greater than 2000 mg/kg. Materials that are essentially non-irritating to the

respiratory tract, eyes and skin. 1 (materials that, under emergency conditions, can

cause significant irritation): Gases and vapors whose LC

for acute inhalation

toxicity is greater than 5,000 ppm but less than or equal to 10,000 ppm. Dusts and

mists whose LC

for acute inhalation toxicity is greater than 10 mg/L but less than or

equal to 200 mg/L. Materials whose LD

for acute dermal toxicity is greater than

1000 mg/kg but less than or equal to 2000 mg/kg. Materials whose LD

for acute

oral toxicity is greater than 500 mg/kg but less than or equal to 2000 mg/kg.

Materials that cause slight to moderate irritation to the respiratory tract, eyes and

skin. 2 (materials that, under emergency conditions, can cause temporary

incapacitation or residual injury): Gases and vapors whose LC

for acute inhalation

toxicity is greater than 3,000 ppm but less than or equal to 5,000 ppm. Dusts and

mists whose LC

for acute inhalation toxicity is greater than 2 mg/L but less than or

equal to 10 mg/L. Materials whose LD

for acute dermal toxicity is greater than 200

mg/kg but less than or equal to 1000 mg/kg. Materials whose LD

for acute oral

toxicity is greater than 50 mg/kg but less than or equal to 500 mg/kg. Any liquid

whose saturated vapor concentration at 20°C (68°F) is equal to or greater than one-

fifth its LC

for acute inhalation toxicity, if its LC

is less than or equal to 5000 ppm

and that does not meet the criteria for either degree of hazard 3 or degree of hazard

4. Compressed liquefied gases with boiling points between -30°C (-22°F) and -55°C

(-66.5°F) that cause severe tissue damage, depending on duration of exposure.

Materials that are respiratory irritants. Materials that cause severe, but reversible

irritation to the eyes or are lachrymators. Materials that are primary skin irritants or

sensitizers. 3 (materials that, under emergency conditions, can cause serious or

permanent injury): Gases and vapors whose LC

for acute inhalation toxicity is

greater than 1,000 ppm but less than or equal to 3,000 ppm. Dusts and mists whose

for acute inhalation toxicity is greater than 0.5 mg/L but less than or equal to 2

mg/L. Materials whose LD

for acute dermal toxicity is greater than 40 mg/kg but

less than or equal to 200 mg/kg. Materials whose LD

for acute oral toxicity is

greater than 5 mg/kg but less than or equal to 50 mg/kg. Any liquid whose saturated

vapor concentration at 20°C (68°F) is equal to or greater than one-fifth its LC

for

acute inhalation toxicity, if its LC

is less than or equal to 3000 ppm and that does

not meet the criteria for degree of hazard 4. Compressed liquefied gases with

boiling points between -30°C (-22°F) and -55°C (-66.5°F) that cause frostbite and

irreversible tissue damage. Materials that are respiratory irritants. Cryogenic gases

that cause frostbite and irreversible tissue damage. Materials that are corrosive to

the respiratory tract. Materials that are corrosive to the eyes or cause irreversible

corneal opacity. Materials that are corrosive to the skin. 4 (materials that, under

emergency conditions, can be lethal): Gases and vapors whose LC

for acute

inhalation toxicity less than or equal to 1,000 ppm. Dusts and mists whose LC

for

acute inhalation toxicity is less than or equal to 0.5 mg/L. Materials whose LD

for

acute dermal toxicity is less than or equal to 40 mg/kg. Materials whose LD

for

acute oral toxicity is less than or equal to 5 mg/kg. Any liquid whose saturated vapor

concentration at 20°C (68°F) is equal to or greater than one-fifth its LC

for acute

inhalation toxicity, if its LC

is less than or equal to 1000 ppm.

NATIONAL FIRE PROTECTION ASSOCIATION HAZARD RATINGS

(continued):

FLAMMABILITY HAZARD: 0 Materials that will not burn under typical fire

conditions, including intrinsically noncombustible materials such as concrete, stone,

and sand: Materials that will not burn in air when exposed to a temperature of 816°C

(1500°F) for a period of 5 minutes in according with Annex D. 1 Materials that must

be preheated before ignition can occur. Materials in this degree require considerable

preheating, under all ambient temperature conditions, before ignition and

combustion can occur: Materials that will burn in air when exposed to a temperature

of 816°C (1500°F) for a period of 5 minutes in accordance with Annex D. Liquids,

solids and semisolids having a flash point at or above 93.4°C (200°F) (i.e. Class IIIB

liquids). Liquids with a flash point greater than 35°C (95°F) that do not sustain

combustion when tested using the Method of Testing for Sustained Combustibility,

per 49 CFR 173, Appendix H or the UN Recommendation on the Transport of

Dangerous Goods, Model Regulations (current edition) and the related Manual of

Tests and Criteria (current edition). Liquids with a flash point greater than 35°C

(95°F) in a water-miscible solution or dispersion with a water non-combustible

liquid/solid content of more than 85 percent by weight. Liquids that have no fire point

when tested by ASTM D 92 Standard Test Method for Flash and Fire Points by

Cleveland Open Cup, up to a boiling point of the liquid or up to a temperature at

which the sample being tested shows an obvious physical change. Combustible

pellets with a representative diameter of greater than 2 mm (10 mesh). Solids

containing greater than 0.5 percent by weight of a flammable or combustible solvent

are rated by the closed up flash point of the solvent. Most ordinary combustible

materials. 2 Materials that must be moderately heated or exposed to relatively high

ambient temperatures before ignition can occur. Materials in this degree would not

under normal conditions form hazardous atmospheres with air, but under high

ambient temperatures or under moderate heating could release vapor in sufficient

quantities to produce hazardous atmospheres with air: Liquids having a flash point at

or above 37.8°C (100°F) and below 93.4°C (200°F) (i.e. Class II and Class IIIA

liquids.) Solid materials in the form of powders or coarse dusts of representative

diameter between 420 microns (40 mesh) and 2 mm (10 mesh) that burn rapidly but

that generally do not form explosive mixtures in air. Solid materials in fibrous or

shredded form that burn rapidly and create flash fire hazards, such as cotton, sisal

and hemp. Solids and semisolids that readily give off flammable vapors. Solids

containing greater than 0.5 percent by weight of a flammable or combustible solvent

are rated by the closed cup flash point of the solvent. 3 Liquids and solids that can

be ignited under almost all ambient temperature conditions. Materials in this degree

produce hazardous atmospheres with air under almost all ambient temperatures or,

though unaffected by ambient temperatures, are readily ignited under almost all

conditions: Liquids having a flash point below 22.8°C (73°F) and having a boiling

point at or above 37.8°C (100°F) and those liquids having a flash point at or above

22.8°C (73°F) and below 37.8°C (73°F) and below 37.8°C (100°F) (i.e. Class IB and

IC liquids). Materials that, on account of their physical form or environmental

conditions, can form explosive mixtures with air and are readily dispersed in air.

Flammable or combustible dusts with a representative diameter less than 420

microns (40 mesh). Materials that burn with extreme rapidity, usually by reason of

self-contained oxygen (e.g. dry nitrocellulose and many organic peroxides). Solids

containing greater than 0.5 percent by weight of a flammable or combustible solvent

are rated by the closed cup flash point of the solvent. 4 Materials that will rapidly or

completely vaporize at atmospheric pressure and normal ambient temperature or

that are readily dispersed in air and will burn readily: Flammable gases. Flammable

cryogenic materials. Any liquid or gaseous materials that is liquid while under

pressure and has a flash point below 22.8°C (73°F) and a boiling point below 37.8°C

(100°F) (i.e. Class IA liquids). Materials that ignite when exposed to air, Solids

containing greater than 0.5 percent by weight of a flammable or combustible solvent

are rated by the closed cup flash point of the solvent.

INSTABILITY HAZARD

: 0 Materials that in themselves are normally stable, even

under fire conditions: Materials that have an estimated instantaneous power density

(product of heat of reaction and reaction rate) at 250°C (482°F) below 0.01 W/mL.

Materials that do not exhibit an exotherm at temperatures less than or equal to 500°C

(932°F) when tested by differential scanning calorimetry. 1 Materials that in

themselves are normally stable, but that can become unstable at elevated

temperatures and pressures: Materials that have an estimated instantaneous power

density (product of heat of reaction and reaction rate) at 250°C (482°F) at or above

0.01 W/mL and below 10 W/mL. 2 Materials that readily undergo violent chemical

change at elevated temperatures and pressures: Materials that have an estimated

instantaneous power density (product of heat of reaction and reaction rate) at 250°C

(482°F) at or above 10 W/mL and below 100W/mL. 3 Materials that in themselves

are capable of detonation or explosive decomposition or explosive reaction, but that

require a strong initiating source or that must be heated under confinement before

initiation: Materials that have an estimated instantaneous power density (product of

heat of reaction and reaction rate) at 250°C (482°F) at or above 100 W/mL and below

1000 W/mL. Materials that are sensitive to thermal or mechanical shock at elevated

temperatures and pressures. 4 Materials that in themselves are readily capable of

detonation or explosive decomposition or explosive reaction at normal temperatures

and pressures: Materials that have an estimated instantaneous power density (product

of heat of reaction and reaction rate) at 250°C (482°F) of 1000 W/mL or greater.

Materials that are sensitive to localized thermal or mechanical shock at normal

temperatures and pressures.