SAFETY DATA SHEET Issuing Date 15-Jun-2015 Revision Date 13-Apr-2016 Revision Number 2 _____________________________________________________________________________________________ The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources.
1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W Revision Date 13-Apr-2016 _____________________________________________________________________________________________ Acute toxicity - Oral Acute toxicity - Inhalation (Gases) Acute toxicity - Inhalation (Vapors) Acute toxicity - Inhalation (Dusts/Mists) Skin corrosion/irritation Serious eye damage/eye irritation Skin sensitization Carcinogenicity Reproductive Toxicity Specific target organ toxicity (single exposure) Specific target organ toxic
1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W Revision Date 13-Apr-2016 _____________________________________________________________________________________________ Specific treatment (see supplemental first aid instructions on this label) Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W Revision Date 13-Apr-2016 _____________________________________________________________________________________________ First aid measures General Advice This is a battery. In case of rupture:. Immediate medical attention is required. Show this safety data sheet to the doctor in attendance. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing.
1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W Revision Date 13-Apr-2016 _____________________________________________________________________________________________ 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient.
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ 7. HANDLING AND STORAGE Precautions for safe handling Handling In case of rupture. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Use personal protection equipment.
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ (vacated) TWA: 2.
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ Lower flammability limit No data available Vapor pressure No data available Vapor density No data available Specific Gravity No data available Water Solubility Insoluble in water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition temperature No data available Decom
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ Eye contact Specific test data for the substance or mixture is not available. Causes burns. (based on components). Corrosive to the eyes and may cause severe damage including blindness. Causes serious eye damage. May cause irreversible damage to eyes.
04983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W Revision Date 13-Apr-2016 _____________________________________________________________________________________________ cause chronic conditions. Contains a known or suspected carcinogen. Contains a known or suspected reproductive toxin. Possible risk of irreversible effects. Avoid repeated exposure. Prolonged exposure may cause chronic effects. Target Organ Effects Aspiration Hazard Eyes. Respiratory system. Skin. Gastrointestinal tract (GI).
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life. Very toxic to aquatic life with long lasting effects. Chemical name Toxicity to Algae Zinc 7440-66-6 Toxicity to Fish Toxicity to Microorganisms 96h EC50: 0.11 - 0.271 96h LC50: = 3.
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal methods This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261).
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ TSCA DSL Complies All components are listed either on the DSL or NDSL.
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ Zinc 7440-66-6 Potassium hydroxide 1310-58-3 Manganese dioxide 1313-13-9 Graphite 7782-42-5 X X X X X X X X X X X X X X International Regulations Chemical name Manganese dioxide Carcinogen Status Exposure Limits Mexico: TWA= 0.2 mg/m3 Steel manufacture, chemicals A3 A2 Mexico: TWA 0.15 mg/m3 Mexico: TWA 0.
Product Safety Data Sheet (PSDS) The battery products referenced in this PSDS document are consumer products. Batteries are considered “articles” under the Global Harmonized System and are exempted from the GHS labeling and SDS classification criteria. This PSDS document is provided as service in response to requests for information on battery use, safety and regulatory compliance.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Manganese Dioxide Propylene Carbonate Lithium Graphite, synthetic 1,2-Dimethoxyethane Lithium Perchlorate CAS Number 1313-13-9 108-32-7 7439-93-2 7440-44-0 110-71-4 7791-03-9 Amount 65-75% 10-15% 5-10% 5-10% 1-10% <1.5% SECTION 4: FIRST AID MEASURES Eye Contact: If battery is leaking and material contacts the eye, flush thoroughly with copious amounts of running water for 30 minutes. Seek immediate medical attention.
ventilation. Carefully collect batteries and place in an appropriate container for disposal. Remove spilled liquid with absorbent and contain for disposal. SECTION 7: HANDLING AND STORAGE Avoid mechanical or electrical abuse. DO NOT short circuit or install incorrectly. Batteries may explode, pyrolize or vent if disassembled, crushed, recharged or exposed to high temperatures. Install batteries in accordance with equipment instructions. Replace all batteries in equipment at the same time.
SECTION 11: TOXICOLOGICAL INFORMATION Acute Toxicity Data: Manganese Dioxide: LD50 oral rat >3478 mg/kg Propylene Carbonate: LD50 oral rat 29100 uL/kg; LD50 dermal rabbit >20 mL/kg; LC50 inhalation rat >5 g/m3 1,2-Dimethoxyethane: LDLo oral rat 1000 mg/kg, LCLo inhalation rat 63 g/m3/6 hr Chronic Effects: The chemicals in this product are contained in a sealed can and exposure does not occur during normal handling and use. No chronic effects would be expected from handling a leaking battery.
SECTION 14: TRANSPORT INFORMATION Emergency Phone Number: CHEMTREC 24‐Hour Emergency Response Hotline +703‐527‐3887 (United States of America) The information in this section is provided for informational purposes only. DURACELL lithium metal batteries are produced and delivered in accordance with IATA 56th ICAO, IMO and US DOT Regulations.
SECTION 15: REGULATORY INFORMATION United States OSHA Status: While the finished product(s) is considered an article and not covered by the OSHA Hazard Communication Standard, 29 CFR 1910.1200, this PSDS contains valuable information critical to the safe handling and proper use of the product". EPA TSCA Status: All intentionally-added components of this product are listed on the US TSCA Inventory.
