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Toner Plastics PLA 3D Printer Filament Page 1 of 7 Rev. 01/01/2015

Material Safety Data Sheet

In accordance with 29 CFR 1910.1200, ANSI Z400.1-2004, and ISO 11014-1: 1994.

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE

COMPANY/UNDERTAKING

Product name: PLA 3D Printer Filament

Product Use: For use in 3D printing machines

Supplier: Toner Plastics 35 Industrial Drive East Longmeadow, MA 01028

Emergency telephone numbers (24 hours a day): (413) 525-2369

2. HAZARDS IDENTIFICATION

Emergency Overview

CAUTION! May cause eye/skin irritation. Burning produces obnoxious and toxic

fumes. Avoid contact with skin and eyes. Avoid formation of dust and aerosols.

Appearance: Clear, translucent, or opaque strand/string.

Color: Varies

Physical state: Solid

Odor: Sweet

Potential health effects:

Eye contact: Contact with eyes may cause irritation.

Skin contact: Substance may cause slight skin irritation.

Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and

diarrhea.

Inhalation: Inhalation of dust may cause shortness of breath, tightness of the

chest, a sore throat and cough. Low hazard for usual handling.

Target organ effects: N/A

Sensitization: N/A

Specific hazards: No information available

Flammability: Fine dust dispersed in air may ignite.

Environmental precautions: Not determined See Section 12 for more

information.

NFPA rating: Data not available

Health: 1

Flammability: 1

Summary of content (7 pages)

PAGE 1
Material Safety Data Sheet In accordance with 29 CFR 1910.1200, ANSI Z400.1-2004, and ISO 11014-1: 1994. 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Product name: PLA 3D Printer Filament Product Use: For use in 3D printing machines Supplier: Toner Plastics 35 Industrial Drive East Longmeadow, MA 01028 Emergency telephone numbers (24 hours a day): (413) 525-2369 2. HAZARDS IDENTIFICATION Emergency Overview CAUTION! May cause eye/skin irritation.
PAGE 2
Reactivity: 0 Special: Not determined HMIS classification: Health: 1 Flammability: 1 Reactivity: 0 Personal Protective Equipment: Not determined 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name: Polylactide resin 9051-89-2 Weight %: >98 OSHA Exposure Limits: None ACGIH Exposure Limits: None All ingredients in quantities > 1.0% (0.1% for carcinogens) that are potentially hazardous per OSHA definitions. Other Standards: N/A 4.
PAGE 3
Suitable extinguishing media: Foam. Water. Carbon dioxide (CO2). Dry chemical. Alcohol resistant foams are preferred if available. General-purpose synthetic foams (including AFFF) or protein foams may function, but much less effectively.
PAGE 4
PERSONAL PROTECTIVE EQUIPMENT: Eye protection: Safety glasses with side-shields. Goggles. Skin and body protection: Impervious clothing. Respiratory protection: Respirator must be worn if exposed to dust. Wear respirator with dust filter. Respiratory protection is needed if any of the exposure limits in Section 2 are exceeded. Consult an industrial hygiene professional prior to respirator selection and use.
PAGE 5
Hazardous decomposition products: Burning produces obnoxious and toxic fumes. Aldehydes. Carbon monoxide (CO). Carbon dioxide (CO2). Polymerization: Not applicable 11. TOXICOLOGICAL INFORMATION Principle Routes of Exposure: Eye contact. Skin contact. Inhalation. Ingestion. Acute toxicity: N/A Local effects: May cause eye/skin irritation. Product dust may be irritating to eyes, skin and respiratory system. Caused mild to moderate conjunctival irritation in eye irritation studies using rabbits.
PAGE 6
used container. Contact manufacturer. THE COMPANY HAS NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION 2 (Composition/Information On Ingredients). Contaminated packaging: Empty remaining contents. Do not re-use empty containers.
PAGE 7
INTERNATIONAL INVENTORIES Canada DSL Inventory List : Not listed REACH/EU EINECS List : Components are in compliance with and/or are listed. Japan (ECL) : Not listed Australia (AICS): Not listed Korean chemical inventory: Not listed Philippines (PICCS) inventory: Not listed China inventory of existing chemical substances list : No listed 16.