Copyright © United Nations, 2008 CHAPTER 3.3 SPECIAL PROVISIONS APPLICABLE TO CERTAIN ARTICLES OR SUBSTANCES 3.3.1 When Column (6) of Table A of Chapter 3.2 indicates that a special provision is relevant to a substance or article, the meaning and requirements of that special provision are as set forth below. 16 Samples of new or existing explosive substances or articles may be carried as directed by the competent authorities (see 2.2.1.1.
Copyright © United Nations, 2008 65 Hydrogen peroxide aqueous solutions with less than 8% hydrogen peroxide are not subject to the requirements of ADN. 103 The carriage of ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt is prohibited. 105 Nitrocellulose meeting the descriptions of UN No. 2556 or UN No. 2557 may be classified in Class 4.1. 113 The carriage of chemically unstable mixtures is prohibited.
Copyright © United Nations, 2008 168 Asbestos which is immersed or fixed in a natural or artificial binder (such as cement, plastics, asphalt, resins or mineral ore) in such a way that no escape of hazardous quantities of respirable asbestos fibres can occur during carriage is not subject to the requirements of ADN.
Copyright © United Nations, 2008 188 Cells and batteries offered for carriage are not subject to other provisions of ADN if they meet the following: (a) For a lithium metal or lithium alloy cell, the lithium content is not more than 1 g, and for a lithium-ion cell, the Watt-hour rating is not more than 20 Wh; (b) For a lithium metal or lithium alloy battery the aggregate lithium content is not more than 2 g, and for a lithium-ion battery, the Watt-hour rating is not more than 100 Wh.
Copyright © United Nations, 2008 (iii) an indication that special procedures shall be followed in the event the package is damaged, to include inspection and repacking if necessary; and (iv) a telephone number for additional information; (h) Except when batteries are installed in equipment, each package shall be capable of withstanding a 1.
Copyright © United Nations, 2008 201 Lighters and lighter refills shall comply with the provisions of the country in which they were filled. They shall be provided with protection against inadvertent discharge. The liquid portion of the gas shall not exceed 85% of the capacity of the receptacle at 15 °C. The receptacles, including the closures, shall be capable of withstanding an internal pressure of twice the pressure of the liquefied petroleum gas at 55 °C.
Copyright © United Nations, 2008 219 Genetically modified micro-organisms and genetically modified organisms which meet the definition of an infectious substance and the criteria for inclusion in Class 6.2 in accordance with section 2.2.62 shall be carried as UN No. 2814, UN No. 2900 or UN No. 3373, as appropriate. 220 Only the technical name of the flammable liquid component of this solution or mixture shall be shown in parentheses immediately following the proper shipping name.
Copyright © United Nations, 2008 236 Polyester resin kits consist of two components: a base material (Class 3, packing group II or III) and an activator (organic peroxide). The organic peroxide shall be type D, E or F, not requiring temperature control. Packing group shall be II or III, according to the criteria for Class 3, applied to the base material. The quantity limit referred to in Column (7a) of Table A of Chapter 3.2 applies to the base material.
Copyright © United Nations, 2008 241 The formulation shall be prepared so that it remains homogeneous and does not separate during carriage. Formulations with low nitrocellulose contents and not showing dangerous properties when tested for their liability to detonate, deflagrate or explode when heated under defined confinement by tests of Test series 1 (a), 2 (b) and 2 (c) respectively in the Manual of Tests and Criteria, Part I and not being a flammable solid when tested in accordance with test No.
Copyright © United Nations, 2008 (b) 251 During carriage, a copy of the document of approval for transport, showing the quantity limitations and the packing provisions shall be attached to the transport document. The entry CHEMICAL KIT or FIRST AID KIT is intended to apply to boxes, cases etc. containing small quantities of various dangerous goods which are used for example for medical, analytical or testing or repair purposes.
Copyright © United Nations, 2008 not exceed 200 °C, when the sample is maintained at a temperature of not less than 75 °C ± 2 °C for a period of 24 hours. 274 The provisions of 3.1.2.8 apply. 278 These substances shall not be classified and carried unless authorized by the competent authority on the basis of results from Series 2 tests and a Series 6(c) test of Part I of the Manual of Tests and Criteria on packages as prepared for carriage (see 2.2.1.1).
Copyright © United Nations, 2008 (b) The generator, without its packaging, shall be capable of withstanding a 1.8 m drop test onto a rigid, non-resilient, flat and horizontal surface, in the position most likely to cause damage, without loss of its contents and without actuation; (c) When a generator is equipped with an actuating device, it shall have at least two positive means of preventing unintentional actuation.
Copyright © United Nations, 2008 295 Batteries need not be individually marked and labelled if the pallet bears the appropriate mark and label. 296 These entries apply for life-saving appliances such as life rafts, personal flotation devices and self-inflating slides. UN No. 2990 applies to self-inflating appliances and UN No. 3072 applies to life-saving appliances that are not self-inflating.
Copyright © United Nations, 2008 309 (a) Not less than 90% ammonium nitrate with not more than 0.2% total combustible/organic material calculated as carbon and with added matter, if any, which is inorganic and inert towards ammonium nitrate; or (b) Less than 90% but more than 70% ammonium nitrate with other inorganic materials or more than 80% but less than 90% ammonium nitrate mixed with calcium carbonate and/or dolomite and/or mineral calcium sulphate and not more than 0.
Copyright © United Nations, 2008 314 (a) These substances are liable to exothermic decomposition at elevated temperatures. Decomposition can be initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt, magnesium) and their compounds); (b) During the course of carriage, these substances shall be shaded from direct sunlight and all sources of heat and be placed in adequately ventilated areas. 315 This entry shall not be used for Class 6.
Copyright © United Nations, 2008 system are regarded as contained in equipment. Fuel cell cartridge means an article that stores fuel for discharge into the fuel cell through (a) valve(s) that control(s) the discharge of fuel into the fuel cell. Fuel cell cartridges, including when contained in equipment, shall be designed and constructed to prevent fuel leakage under normal conditions of carriage.
Copyright © United Nations, 2008 339 (a) Be capable of withstanding, without leakage or bursting, a pressure of at least two times the equilibrium pressure of the contents at 55 ºC; (b) Not contain more than 200 ml of liquefied flammable gas with a vapour pressure not exceeding 1 000 kPa at 55 °C; and (c) Pass the hot water bath test prescribed in 6.2.6.3.1 of ADR.
Copyright © United Nations, 2008 rated charging pressure. The fuel cell cartridge shall then be hydrostatically pressurized to destruction. The recorded burst pressure shall exceed 85% of the minimum shell burst pressure. Fire test A fuel cell cartridge filled to rated capacity with hydrogen shall be subjected to a fire engulfment test.
Copyright © United Nations, 2008 not individually authorized as excepted quantities in column 7b of Table A of Chapter 3.2, are authorized in such kits and are assigned Code E2 (see 3.5.1.2). 341-499 (Reserved) 500 UN No. 3064 nitroglycerin, solution in alcohol with more than 1% but not more than 5% nitroglycerin, packed in accordance with packing instruction P300 of 4.1.4.1 of ADR, is a substance of Class 3. 501 For naphthalene, molten, see UN No. 2304. 502 UN No.
Copyright © United Nations, 2008 UN No. 1565 barium cyanide and UN No. 1884 barium oxide are substances of Class 6.1. 514 UN No. 2464 beryllium nitrate is a substance of Class 5.1. 515 UN No. 1581 chloropicrin and methyl bromide mixture and UN No. 1582 chloropicrin and methyl chloride mixture are substances of Class 2. 516 UN No. 1912 methyl chloride and methylene chloride mixture is a substance of Class 2. 517 UN No. 1690 sodium fluoride, solid, UN No. 1812 potassium fluoride, solid, UN No.
Copyright © United Nations, 2008 531 Mixtures having a flash-point below 23 °C and containing more than 55% nitrocellulose, whatever its nitrogen content or containing not more than 55% nitrocellulose with a nitrogen content above 12.6% (by dry mass), are substances of Class 1 (see UN Nos. 0340 or 0342) or of Class 4.1. 532 UN No. 2672 ammonia solution containing not less than 10% but not more than 35% ammonia is a substance of Class 8. 533 UN No.
Copyright © United Nations, 2008 547 UN No. 2210 maneb or UN No. 2210 maneb preparations in self-heating form are substances of Class 4.2. 548 Chlorosilanes which, in contact with water, emit flammable gases, are substances of Class 4.3. 549 Chlorosilanes having a flash-point of less than 23 °C and which, in contact with water, do not emit flammable gases are substances of Class 3.
Copyright © United Nations, 2008 562 Spontaneously combustible organometallic compounds are substances of Class 4.2. Water-reactive organometallic compounds, flammable, are substances of Class 4.3. 563 UN No. 1905 selenic acid is a substance of Class 8. 564 UN No. 2443 vanadium oxytrichloride, UN No. 2444 vanadium tetrachloride and UN No. 2475 vanadium trichloride are substances of Class 8.
Copyright © United Nations, 2008 Mixture F3, have a vapour pressure at 70 °C not exceeding 3 MPa (30 bar) and a density at 50 °C not lower than that of chlorodifluoromethane (1.09 kg/l). NOTE: Trichlorofluoromethane (refrigerant R 11), 1,1,2-trichloro-1,2,2trifluoroethane (refrigerant R 113), 1,1,1-trichloro-2,2,2-trifluoroethane (refrigerant R 113a), 1-chloro-1,2,2-trifluoroethane (refrigerant R 133) and 1-chloro-1,1,2trifluoroethane (refrigerant R 133 b) are not substances of Class 2.
Copyright © United Nations, 2008 – "Mixture B2"; – "Mixture B"; – "Mixture C" or "Propane". For carriage in tanks, the trade names "butane" or "propane" may be used only as a complement. 584 This gas is not subject to the requirements of ADN when: – it is in the gaseous state; – it contains not more than 0.
Copyright © United Nations, 2008 – UN No. 1044 fire extinguishers provided with protection against inadvertent discharge; – UN No. 3164 articles, pressurized pneumatic or hydraulic, designed to withstand stresses greater than the internal gas pressure by virtue of transmission of force, intrinsic strength or construction. 596 Cadmium pigments, such as cadmium sulphides, cadmium sulphoselenides and cadmium salts of higher fatty acids (e.g. cadmium stearate), are not subject to the requirements of ADN.
Copyright © United Nations, 2008 603 Anhydrous hydrogen cyanide not meeting the description for UN No. 1051 or UN No. 1614 is not to be accepted for carriage. Hydrogen cyanide (hydrocyanic acid) containing less than 3% water is stable, if the pH-value is 2.5 ± 0.5 and the liquid is clear and colourless. 604 Ammonium bromate and its aqueous solutions and mixtures of a bromate with an ammonium salt are not to be accepted for carriage.
Copyright © United Nations, 2008 minimum temperature of the product of 32.5 °C" shall appear in the transport document. 625 Packages containing these articles shall be clearly marked as follows: "UN 1950 AEROSOLS" 626-631 (Reserved) 632 Considered to be spontaneously flammable (pyrophoric). 633 Packages and small containers containing this substance shall bear the following marking: "Keep away from any source of ignition".
Copyright © United Nations, 2008 639 See 2.2.2.3, classification code 2F, UN No. 1965, Note 2. 640 The physical and technical characteristics mentioned in column (2) of Table A of Chapter 3.2 determine different tank codes for the carriage of substances of the same packing group in tanks conforming to Chapter 6.8 of RID or ADR.
Copyright © United Nations, 2008 hermetically sealed by the person in charge of packaging and/or filling so that under normal conditions of carriage there will be no leakage; (e) Combination packagings with inner packaging made of glass or plastic (see packing instruction P001 in 4.1.4.1 of ADR) which fulfil the general packing requirements of 4.1.1.1, 4.1.1.2, 4.1.1.4, 4.1.1.5, 4.1.1.6, 4.1.1.7 and 4.1.1.
Copyright © United Nations, 2008 653 The carriage of this gas in cylinders with a maximum capacity of 0.5 litres, is not subject to the other provisions of ADN if the following conditions are met: - The provisions for construction and testing of cylinders are observed; - The cylinders are contained in outer packagings which at least meet the requirements of Part 4 for combination packagings. The general provisions of packing of 4.1.1.1, 4.1.1.2 and 4.1.1.5 to 4.1.1.
Copyright © United Nations, 2008 801 Ferrosilicon with between 25 and 30% or more than 90% silicon content by mass is a dangerous substance of Class 4.3 for carriage in bulk or without packaging by inland navigation vessel. 802 See 7.1.4.10.
