Material Safety Data Sheet SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: DURACELL ALKALINE BATTERIES Product Identification: Alkaline Manganese Dioxide Cells – Duracell Designations: 7K67; MN1203; MN1300; MN1400; MN1500; MN2400; MN1604; MN908; MN918; MN9100; MX1604; MX2500; MX1300; MX1400; MX1500; MX2400 Product Use: Energy Source MSDS Date of Preparation: August 24, 2009 Company Identification US Office Duracell, a division of P&G Berkshire Corporate Park 14 Research Drive Bethel, CT USA 0640
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Manganese Dioxide Zinc Potassium Hydroxide (35%) Graphite (natural or synthetic) CAS Number 1313-13-9 7440-66-6 1310-58-3 7782-42-5, 7440-44-0 Amount 35-40% 10-25% 5-10% 1-5% SECTION 4: FIRST AID MEASURES Eye Contact: If battery is leaking and material contacts the eye, flush thoroughly with copious amounts of running water for 30 minutes. Seek immediate medical attention.
SECTION 7: HANDLING AND STORAGE Avoid mechanical or electrical abuse. DO NOT short circuit or install incorrectly. Batteries may explode, pyrolize or vent if disassembled, crushed, recharged or exposed to high temperatures. Install batteries in accordance with equipment instructions. Do not mix battery systems, such as alkaline and zinc carbon, in the same equipment. Replace all batteries in equipment at the same time. Do not carry batteries loose in a pocket or bag.
Hazardous Decomposition Products: Thermal decomposition may produce hazardous fumes of zinc and manganese; caustic vapors of potassium hydroxide and other toxic by-products. Hazardous Polymerization: Will not occur SECTION 11: TOXICOLOGICAL INFORMATION Acute Toxicity Data: Manganese Dioxide: LD50 oral rat >3478 mg/kg Potassium Hydroxide: LD50 oral rat 273 mg/kg Chronic Effects: The chemicals in this product are contained in a sealed can and exposure does not occur during normal handling and use.
Special provisions apply and shippers should consult the most current versions of the transportation regulations. Special Provision A123 in the IATA Dangerous Goods Regulations and ICAO Technical Instructions and Special Provision 130 in 49 CFR 172.102 of the U.S. DOT regulations require alkaline batteries be packed in such a way to prevent short circuits or generating a dangerous quantity of heat.
Data supplied is for use only in connection with occupational safety and health. DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the use of this material. The information contained here has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. It is not meant to be an all-inclusive document on worldwide hazard communication regulations. This information is offered in good faith.
SAFETY DATA SHEET Issuing Date 15-Jun-2015 Revision Date 13-Apr-2016 Revision Number 2 _____________________________________________________________________________________________ The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources.
1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W Revision Date 13-Apr-2016 _____________________________________________________________________________________________ Acute toxicity - Oral Acute toxicity - Inhalation (Gases) Acute toxicity - Inhalation (Vapors) Acute toxicity - Inhalation (Dusts/Mists) Skin corrosion/irritation Serious eye damage/eye irritation Skin sensitization Carcinogenicity Reproductive Toxicity Specific target organ toxicity (single exposure) Specific target organ toxic
1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W Revision Date 13-Apr-2016 _____________________________________________________________________________________________ Specific treatment (see supplemental first aid instructions on this label) Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
04983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W Revision Date 13-Apr-2016 _____________________________________________________________________________________________ First aid measures General Advice This is a battery. In case of rupture:. Immediate medical attention is required. Show this safety data sheet to the doctor in attendance. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing.
1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W Revision Date 13-Apr-2016 _____________________________________________________________________________________________ 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient.
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ 7. HANDLING AND STORAGE Precautions for safe handling Handling In case of rupture. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Use personal protection equipment.
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ (vacated) TWA: 2.
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ Lower flammability limit No data available Vapor pressure No data available Vapor density No data available Specific Gravity No data available Water Solubility Insoluble in water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition temperature No data available Decom
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ Eye contact Specific test data for the substance or mixture is not available. Causes burns. (based on components). Corrosive to the eyes and may cause severe damage including blindness. Causes serious eye damage. May cause irreversible damage to eyes.
1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W Revision Date 13-Apr-2016 _____________________________________________________________________________________________ cause chronic conditions. Contains a known or suspected carcinogen. Contains a known or suspected reproductive toxin. Possible risk of irreversible effects. Avoid repeated exposure. Prolonged exposure may cause chronic effects. Target Organ Effects Aspiration Hazard Eyes. Respiratory system. Skin. Gastrointestinal tract (GI).
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life. Very toxic to aquatic life with long lasting effects. Chemical name Toxicity to Algae Zinc 7440-66-6 Toxicity to Fish Toxicity to Microorganisms 96h EC50: 0.11 - 0.271 96h LC50: = 3.
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal methods This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261).
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ TSCA DSL Complies All components are listed either on the DSL or NDSL.
Revision Date 13-Apr-2016 1004983 - E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W _____________________________________________________________________________________________ Zinc 7440-66-6 Potassium hydroxide 1310-58-3 Manganese dioxide 1313-13-9 Graphite 7782-42-5 X X X X X X X X X X X X X X International Regulations Chemical name Manganese dioxide Carcinogen Status Exposure Limits Mexico: TWA= 0.2 mg/m3 Steel manufacture, chemicals A3 A2 Mexico: TWA 0.15 mg/m3 Mexico: TWA 0.
Document Number: Alkaline_Dry_CH_SDS_01_15 SAFETY DATA SHEET In Accordance with OSHA Standard 1910.1200 App D (USA) 1. Identification (a) Product identifier used on the label: LR03(GD) / AAA / 1.5V LR6(GD) / AA / 1.
Document Number: Alkaline_Dry_CH_SDS_01_15 SAFETY DATA SHEET and the mixture is not classified based on testing of the mixture as a whole, a statement that X% of the mixture consists of ingredient(s) of unknown acute toxicity is required No such an ingredient is contained in the product. 3. Composition/information on ingredients Except as provided for in paragraph (i) of §1910.
Document Number: Alkaline_Dry_CH_SDS_01_15 SAFETY DATA SHEET (1) Are present above their cut-off/concentration limits; or (2) Present a health risk below the cut-off/concentration limits. No such an ingredient is contained in the product. (b) The concentration (exact percentage) shall be specified unless a trade secret claim is made in accordance with paragraph (i) of §1910.
Document Number: Alkaline_Dry_CH_SDS_01_15 SAFETY DATA SHEET Carbon dioxide (CO2), foam, or dry chemical powder extinguishing media is suitable. (b) Specific hazards arising from the chemical (e.g., nature of any hazardous combustion products). The product is not inflammable; the liquid, if leaked from the product, may cause corrosion to paper, plastic, or any other tender material(s) near by. (c) Special protective equipment and precautions for fire-fighters.
Document Number: Alkaline_Dry_CH_SDS_01_15 SAFETY DATA SHEET N/A (b) Appropriate engineering controls. Do not disassemble the product without professional basis. (c) Individual protection measures, such as personal protective equipment. No special equipment is required for handling, carrying or using the product. The chemical materials concluded in the Product is sealed up, thus being stable, safe and eco-friendly under common conditions. 9.
Document Number: Alkaline_Dry_CH_SDS_01_15 SAFETY DATA SHEET (p) Auto-ignition temperature : not applicable (q) Decomposition temperature : not applicable (r) Viscosity : not applicable 10. Stability and reactivity (a) Reactivity N/A (b) Chemical stability Stable. The chemical materials concluded in the Product are sealed up, thus being stable, safe and eco-friendly under common conditions. (c) Possibility of hazardous reactions No. (d) Conditions to avoid (e.g.
Document Number: Alkaline_Dry_CH_SDS_01_15 SAFETY DATA SHEET (b) Symptoms related to the physical, chemical and toxicological characteristics People might feel itching, if the inner liquid splashes onto skin.
Document Number: Alkaline_Dry_CH_SDS_01_15 SAFETY DATA SHEET packaging” that prevents spillage of contents. All original packaging for Maxell alkaline batteries has been designed to be compliant with these regulatory concerns.
Document Number: Alkaline_Dry_CH_SDS_01_15 SAFETY DATA SHEET 15. Regulatory information (Non-mandatory) Safety, health and environmental regulations specific for the product in question The product is eco-friendly and in accordance with the safety regulations in ANSI C18.1M_ Part2 Standard, and complying with the environmental requirements in EU Directives 2006/66/EC (Battery Directive). 16.